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404985

Sigma-Aldrich

Titanium(IV) chloride solution

0.09 M in 20% HCl

Synonym(s):

Titanium tetrachloride

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About This Item

Linear Formula:
TiCl4
CAS Number:
7550-45-0
Molecular Weight:
189.68
MDL number:
MFCD00011267
UNSPSC Code:
12352300
PubChem Substance ID:
329755994
NACRES:
NA.21

form

liquid

Quality Level

100

reaction suitability

reagent type: catalyst
core: titanium

concentration

0.09 M in 20% HCl

density

1.099 g/mL at 25 °C

SMILES string

Cl[Ti](Cl)(Cl)Cl

InChI

1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

InChI key

XJDNKRIXUMDJCW-UHFFFAOYSA-J

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Application

Reagent for the detection of peroxides in ethyl ether. Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.
Titanium(IV) chloride (TiCl4) solution may be used to synthesize nanosized titanium dioxide and nano/micro-sized titania powders.

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H290,H314,H335

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

404985-100ML:4548173146225
404985-800ML:4548173146232
404985-4X100ML:
404985-BULK:
404985-VAR:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Reagent Chemicals (1992)
Influence of solution concentration on the hydrothermal preparation of titania crystallites.
Yanqing Z, et al.
Journal of Materials Chemistry, 11(5), 1547-1551 (2001)
Mechanism of enhanced performance of dye-sensitized solar cell based TiO2 films treated by titanium tetrachloride.
Long-Yue Z, et al.
Chinese Physics Letters, 21(9), 1835-1835 (2004)
Titanium tetrachloride promoted hydrolysis of cephalosporin tert-butyl esters.
Valencic M, et al.
Tetrahedron Letters, 39(12), 1625-1628 (1998)
Precipitation of nanosized titanium dioxide from aqueous titanium (IV) chloride solutions by neutralization with MgO.
Li Y and Demopoulos GP.
Hydrometallurgy, 90(1), 26-33 (2008)
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