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238597

Sigma-Aldrich

Sodium sulfate

ACS reagent, ≥99.0%, anhydrous, powder

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About This Item

Linear Formula:
Na2SO4
CAS Number:
7757-82-6
Molecular Weight:
142.04
EC Number:
231-820-9
MDL number:
MFCD00003504
UNSPSC Code:
12352302
PubChem Substance ID:
329752510
NACRES:
NA.21

grade

ACS reagent
anhydrous

Quality Level

200

Assay

≥99.0%

form

powder

impurities

≤0.01% insolubles
≤5 ppm N compounds

loss

≤0.5% loss on ignition

pH

5.2-9.2 (25 °C, 5% in water)
5.2-9.2

mp

884 °C (lit.)

density

2.68 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤0.001%
phosphate (PO43-): ≤0.001%

cation traces

Ca: ≤0.002%
Fe: ≤0.001%
K: ≤0.002%
Mg: ≤0.001%
heavy metals: ≤5 ppm (by ICP-OES)

SMILES string

[Na+].[Na+].[O-]S([O-])(=O)=O

InChI

1S/2Na.H2O4S/c;;1-5(2,3)4/h;;(H2,1,2,3,4)/q2*+1;/p-2

InChI key

PMZURENOXWZQFD-UHFFFAOYSA-L

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Application

Sodium sulfate can be used as a catalyst:
  • In the Suzuki-Miyaura cross-coupling reactions of aryl halides with arylboronic acids to synthesize biaryl compounds in the presence of PdCl2.
  • For the aminolytic depolymerization of PET (polyethylene terephthalate) bottle waste.
It can also be used as an additive in the Pd-catalyzed Sonogashira reaction of terminal alkynes with aryl halides to synthesize polyfunctional alkynes.

Other Notes

Go to Redi-Dri™ Product Listing 746363

Legal Information

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

238597-1KG:
238597-500G:4548173122564
238597-2.5KG:4548173122540
238597-6X500G:
238597-25G:4548173122557
238597-BULK:
238597-12KG:4548173122533
238597-VAR:
238597-36X500G:
238597-5KG:
QR-020-500G:
238597-25KG:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Eagleson M.
Concise Encyclopedia Chemistry, 405-405 (1994)
How does sodium sulfate crystallize? Implications for the decay and testing of building materials.
Rodriguez-Navarro C, et al.
Cement and Concrete Research, 30(10), 1527-1534 (2000)
The use of sodium sulfate as the globulin precipitant in the determination of proteins in blood.
Howe PE.
The Journal of Biological Chemistry, 49(1), 93-107 (1921)
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Water research, 47(2), 661-671 (2012-11-24)
Release of lead from 80% partially replaced service lines was compared to full lead service lines using harvested-stabilized lead pipes and field brass connectors. After more than a year of stabilization, lead release was consistent with field samples. Over the
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