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233714

Sigma-Aldrich

Sodium bisulfate monohydrate

ReagentPlus®, 99%

Synonym(s):

Sodium hydrogen sulfate monohydrate

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About This Item

Linear Formula:
NaHSO4 · H2O
CAS Number:
Molecular Weight:
138.08
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.55

product line

ReagentPlus®

Assay

99%

form

moist crystals

SMILES string

[Na+].[H]O[H].OS([O-])(=O)=O

InChI

1S/Na.H2O4S.H2O/c;1-5(2,3)4;/h;(H2,1,2,3,4);1H2/q+1;;/p-1

InChI key

JXHZRQHZVYDRGX-UHFFFAOYSA-M

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General description

Sodium bisulfate monohydrate can be used as a reagent for the oxidation of benzylic alcohols to aldehydes and ketones, diarylcarbazides to diaryl carbazones, 1,2-dihydroquinolines to quinoline derivatives, and 1,4-dihydropyridines to pyridine derivatives. It can also be used as a catalyst in the esterification of carboxylic acids and alcohols to synthesize esters. Additionally, it is an effective oxygen scavenger to inhibit corrosion.

Application


  • Preservative and Sanitizer in Food Microbiology: Sodium bisulfate monohydrate is effectively used as a preservative in apple juice and as an alternative sanitizer for washing cherry tomatoes. Its antimicrobial properties help control pathogens like Listeria monocytogenes and Escherichia coli, ensuring food safety. This application is crucial for chemists working in food microbiology and safety, highlighting the compound′s role in maintaining the quality and safety of food products (Chen et al., International Journal of Food Microbiology, 2022).

  • One-Step Hydrolysis for Xylooligosaccharides Production: Sodium bisulfate monohydrate is employed in a one-step hydrolysis process for the efficient production of xylooligosaccharides from poplar. This method enhances the yield and purity of xylooligosaccharides, which are valuable in various industrial applications, including food additives and pharmaceuticals. This research underscores its importance in bioprocessing and green chemistry initiatives (Liao et al., SSRN Electronic Journal, 2022).

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Precautionary Statements

Hazard Classifications

Eye Dam. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

233714-1KG:
233714-BULK:
233714-VAR:
233714-100G:
233714-500G:
233714-5G:


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Oxidation of 1, 4-dihydropyridines under mild and heterogeneous conditions
Zolfigol M, et al.
Synthetic Communications, 30, 2945-2950 (2000)
NaBrO3/NaHSO4.H2O as a versatile reagent system for the oxidation of benzylic alcohols and aldehydes
Shirini F, et al.
Synthetic Communications, 36, 2833-2840 (2006)
Synthesis of 2, 4-D butylate with Sodium Bisulfate Catalyst [J].
Wang Y and Zhang W.
Chemical World, 3, 15-15 (2009)
Catalytic esterifications of carboxylic acids and alcohols by sodium bisulfate monohydrate
Li Y
Synthetic Communications, 29, 3901-3903 (1999)
Oxidation of 1, 2-dihydroquinolines under mild and heterogeneous conditions
Damavandi J, et al.
Synthetic Communications, 31, 3183-3187 (2001)

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