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73879

Supelco

Piperonylbutoxide-(butyl-d9)

PESTANAL®, analytical standard

Synonym(s):

2-[2-(Butoxy-d9)ethoxy]ethyl (6-propylpiperonyl) ether, 4,5-Methylenedioxy-2-propylbenzyldiethyleneglycol butyl-d9 ether, Piperonylbutoxide-d9

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About This Item

Empirical Formula (Hill Notation):
C19D9H21O5
CAS Number:
1329834-53-8
Molecular Weight:
347.49
UNSPSC Code:
77101502
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

Assay

≥97.0% (HPLC)

shelf life

limited shelf life, expiry date on the label

application(s)

agriculture
environmental

format

neat

General description

Piperonylbutoxide-(butyl-d9) is an isotope labeled analog of the insecticide synergist piperonyl butoxide, wherein the butoxy protons are replaced by deuterium.

Application

Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The major advantage of using this technique is that the isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analogs, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis, potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Environment
GHS09

Signal Word

Warning

Hazard Statements

H410

Precautionary Statements

P273 - P391 - P501

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

73879-VAR:
73879-BULK:
73879-10MG:

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL6836
BCCD9403
BCCD6557
BCCC0300
BCBV6068

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Electrochemical behavior and determination of the insecticide synergist piperonyl butoxide
Coomber DC, et al.
Analytical Chemistry, 69(5), 898-903 (1997)

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