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Safety Information

32931

Supelco

Vamidothion solution

100 μg/mL in acetonitrile, PESTANAL®, analytical standard

Synonym(s):

O,O-Dimethyl S-[2-(1-methyl-2-methylamino-2-oxoethylthio)ethyl] phosphorothioate

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About This Item

Empirical Formula (Hill Notation):
C8H18NO4PS2
CAS Number:
2275-23-2
Molecular Weight:
287.34
EC Number:
200-835-2
MDL number:
MFCD00055442
UNSPSC Code:
41116107
PubChem Substance ID:
329754394
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

concentration

100 μg/mL in acetonitrile

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture

format

single component solution

storage temp.

2-8°C

SMILES string

CNC(=O)C(C)SCCSP(=O)(OC)OC

InChI

1S/C8H18NO4PS2/c1-7(8(10)9-2)15-5-6-16-14(11,12-3)13-4/h7H,5-6H2,1-4H3,(H,9,10)

InChI key

LESVOLZBIFDZGS-UHFFFAOYSA-N

General description

Vamidothion belongs to the class of organophosphorus pesticides (OPs) which act as cholinesterase inhibitors and are utilized for protection of crops against spiders, mites, aphids, beetles, caterpillars, etc.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Vamidothion may be used as an analytical reference standard for the determination of the analyte in:
  • Aqueous samples by direct injection using liquid chromatography–tandem mass spectrometry (LC-MS/MS) as well as hydrophilic interaction liquid chromatography (HILIC) with MS/MS.
  • Biological samples by gas chromatography in conjunction with mass-selective detection (GC-MSD).

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

35.6 °F - closed cup

Flash Point(C)

2 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

FSL

Group 4: Flammable liquids
Type 1 petroleums
Hazardous rank II
Water insoluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

32931-VAR:
32931-BULK:
32931-2ML:4548173302928

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Certificates of Analysis (COA)

Lot/Batch Number
BCCF0212
BCBR5672V
SZBF127XV
SZBD332XV
SZBB024XV

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Multiresidue determination method for organophosphorus pesticides in serum and whole blood by gas chromatography-mass-selective detection.
Lacassie E, et al.
Journal of Chromatography. B, Biomedical Sciences and Applications, 759(1), 109-116 (2001)
H A Cabrera et al.
Journal of agricultural and food chemistry, 48(11), 5750-5753 (2000-11-23)
The objective of this research was to study the residual levels of benomyl, methyl parathion, diuron, and vamidothion in pineapple bagasse and pulp. Benomyl (benlate), methyl parathion (Folidol 600), diuron (Krovar), and Vamidothion (Kilval 300) were applied pre-harvest to pineapples
Determination of polar organophosphorus pesticides in aqueous samples by direct injection using liquid chromatography-tandem mass spectrometry.
Ingelse BA, et al.
Journal of Chromatography A, 918(1), 67-78 (2001)
Tadashi Hayama et al.
Rapid communications in mass spectrometry : RCM, 22(14), 2203-2210 (2008-06-11)
A method combining hydrophilic interaction liquid chromatography (HILIC) with tandem mass spectrometry (MS/MS) was developed for the determination of polar organophosphorus pesticides (OPPs; acephate, methamidophos, monocrotophos, omethoate, oxydemeton-methyl, and vamidothion) in water samples. To extract the polar OPPs and minimize

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