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Safety Information

13180

Supelco

Benzylamine

for GC derivatization, LiChropur™, ≥99.0%

Synonym(s):

α-Aminotoluene

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About This Item

Linear Formula:
C6H5CH2NH2
CAS Number:
100-46-9
Molecular Weight:
107.15
Beilstein:
741984
EC Number:
202-854-1
MDL number:
MFCD00008106
UNSPSC Code:
12000000
eCl@ss:
39030404
PubChem Substance ID:
329750088
NACRES:
NA.22

grade

for GC derivatization

Quality Level

100

Assay

≥99.0% (GC)
≥99.0%

form

liquid

quality

LiChropur™

technique(s)

gas chromatography (GC): suitable

refractive index

n20/D 1.543 (lit.)
n20/D 1.543

bp

184-185 °C (lit.)

mp

10 °C (lit.)

solubility

H2O: soluble

density

0.981 g/mL at 25 °C (lit.)

SMILES string

NCc1ccccc1

InChI

1S/C7H9N/c8-6-7-4-2-1-3-5-7/h1-5H,6,8H2

InChI key

WGQKYBSKWIADBV-UHFFFAOYSA-N

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General description

Benzylamine, a primary amine, can be used as a fluorescence derivatization agent for the sensitive and selective determination of analytes by chromatography techniques coupled with fluorescence detection.

Application

Benzylamine may be used as a derivatization agent to increase the sensitivity of 5-hydroxyindoles, catecholamines and catechols in biological samples prior to their determination using high performance liquid chromatography (HPLC) coupled with fluorescence detection.

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Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302 + H312,H314

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

149.0 °F - closed cup

Flash Point(C)

65 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 2 petroleums
Hazardous rank III
Water soluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

13180-BULK:
13180-100ML:
13180-500ML:
13180-1ML-KC:
13180-10X1ML:
13180-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
BCCM4389
BCCL4617
BCCK0792
BCCK6435
BCCH2116

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Simultaneous determination of norepinephrine, serotonin, and 5-hydroxyindole-3-acetic acid in microdialysis samples from rat brain by microbore column liquid chromatography with fluorescence detection following derivatization with benzylamine
Yoshitake T, et al.
Analytical Biochemistry, 312(2), 125-133 (2003)
The Derivatization of Proquinoidal Analytes with 1, 2-Diphenylethane-1, 2-Diamine (DPE) and Benzylamine (BA): An Investigation of Products, Yields, Kinetics and Reagent Selectivity
Woods JM, et al.
Chromatographia, 78(3-4), 163-178 (2015)
Kaoru Fujino et al.
Journal of chromatography. A, 1012(2), 169-177 (2003-10-03)
A highly selective and sensitive method for the simultaneous determination of 5-hydroxyindoles and catechols (serotonin, norepinephrine, dopamine and related compounds) by high-performance liquid chromatography with fluorescence detection is described. The method is based on the two-step precolumn derivatization of 5-hydroxyindoles
Saioa Gomez-Zorita et al.
Journal of physiology and biochemistry, 69(3), 585-593 (2013-01-15)
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Organic letters, 13(1), 11-13 (2010-12-02)
A versatile synthesis of unsaturated seven-membered ring lactams has been developed. The sequence involves hydroamination of Baylis-Hillman acetate with amines, followed by intramolecular cyclocarbonylation reactions of the resulting allylamines. This process can tolerate a wide array of functional groups, and
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