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101036

Sigma-Aldrich

1-(2-Pyridylazo)-2-naphthol

indicator grade

Synonym(s):

PAN

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About This Item

Empirical Formula (Hill Notation):
C15H11N3O
CAS Number:
Molecular Weight:
249.27
Beilstein:
206390
EC Number:
MDL number:
UNSPSC Code:
12171500
PubChem Substance ID:
NACRES:
NA.47

grade

indicator grade

Quality Level

form

solid

technique(s)

titration: suitable

color

green to red, upon chelation with metal
orange-red, as an amorphous solid
yellow, when dissolved in organic solvent

mp

138-141 °C ((280 - 286 °F) - lit)
138-141 °C (lit.)

ε (extinction coefficient)

≥15000 at 462-468 nm in methanol at 0.01 g/L
>35,000 at 222-228 nm in methanol at 0.01 g/L
>9,000 at 300-306 nm in methanol at 0.01 g/L

suitability

suitable for (Suitable For Use as an Indicator in EDTA Titrations)

SMILES string

Oc1ccc2ccccc2c1\N=N\c3ccccn3

InChI

1S/C15H11N3O/c19-13-9-8-11-5-1-2-6-12(11)15(13)18-17-14-7-3-4-10-16-14/h1-10,19H/b18-17+

InChI key

LLYOXZQVOKALCD-ISLYRVAYSA-N

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General description

1-(2-Pyridylazo)-2-naphthol (PAN) is an orange-colored dye. It can form chelates with metal ions, which makes it a valuable indicator in complexometric titrations.

Application

1-(2-Pyridylazo)-2-naphthol is commonly used as an acid-base indicator. It is also suitable as a spectrophotometric reagent, which can extract metal chelates into an organic solvent.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

101036-25G:
101036-5G:
101036-BULK:
101036-1G:
101036-VAR:


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Fresenius Journal of Analytical Chemistry, 329, 750-750 (1988)
Solvent extraction and spectrophotometric determination of metals with 1-(2-pyridylazo)-2-naphthol.
Shibata S.
Analytica Chimica Acta, 25(1), 348-359 (1961)
Spectrophotometric Investigation of Analytical Reagent 1-(2-Pyridylazo)-2-naphthol and Its Copper Chelate.
Pease BF and Williams MB.
Analytical Chemistry, 31(6), 1044-1047 (1959)
1-(2-Pyridylazo)-2-naphthol as possible analytical reagent.
Cheng KL and Bray RH.
Analytical Chemistry, 27(5), 782-785 (1955)
Microchemical Journal, Devoted to the Application of Microtechniques in All Branches of Science, 40, 94-94 (1989)

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