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Safety Information

13-0730

Sigma-Aldrich

Hexamethylenediamine

SAJ first grade, ≥98.0%

Synonym(s):

1,6-Diaminohexane, 1,6-Hexanediamine, HMDA

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About This Item

Linear Formula:
NH2(CH2)6NH2
CAS Number:
124-09-4
Molecular Weight:
116.20
Beilstein:
1098307
EC Number:
204-679-6
MDL number:
MFCD00008243
UNSPSC Code:
12352116
PubChem Substance ID:
329749993
grade:
SAJ first grade
Assay:
≥98.0%

grade

SAJ first grade

vapor density

4 (vs air)

Assay

≥98.0%

form

solid

expl. lim.

6.3 %

availability

available only in Japan

refractive index

n20/D 1.439 (lit.)

pH

12.4 (25 °C, 100 g/L)

mp

42-45 °C (lit.)

density

0.89 g/mL at 25 °C (lit.)

SMILES string

NCCCCCCN

InChI

1S/C6H16N2/c7-5-3-1-2-4-6-8/h1-8H2

InChI key

NAQMVNRVTILPCV-UHFFFAOYSA-N

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Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302 + H312,H314,H335

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

176.0 °F - closed cup

Flash Point(C)

80 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

PRTR

Class I Designated Chemical Substances

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

13-0730-2-25G-J:
13-0730-5-500G-J:

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Certificates of Analysis (COA)

Lot/Batch Number
A0447
A2371
A9268
A1247
A7169

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Wei-Chiang Chen et al.
ACS applied materials & interfaces, 1(8), 1821-1826 (2010-04-02)
Solvent microenvironments are formed around individual single-walled carbon nanotubes (SWNTs) by mixing SWNT suspensions with water-immiscible organic solvents. These microenvironments are used to encapsulate the SWNTs with the monomer sebacoyl chloride. Hexamethylene diamine is then injected into the aqueous phase
Junseok Yeom et al.
Bioconjugate chemistry, 21(2), 240-247 (2010-01-19)
A novel, biocompatible, and nontoxic dermal filler using hyaluronic acid (HA) hydrogels was successfully developed for tissue augmentation applications. Instead of using highly reactive cross-linkers such as divinyl sulfone (DVS) for Hylaform, 1,4-butanediol diglycidyl ether (BDDE) for Restylane, and 1,2,7,8-diepoxyoctane
Richard F G Fröhlich et al.
Carbohydrate research, 346(12), 1592-1598 (2011-06-08)
Two simple and reliably accessible intermediates, N-carboxypentyl- and N-aminohexyl-1-deoxy-D-galactonojirimycin were employed for the synthesis of a set of terminally N-dansyl substituted derivatives. Reaction of the terminal carboxylic acid of N-carboxypentyl-1-deoxy-D-galactonojirimycin with N-dansyl-1,6-diaminohexane provided the chain-extended fluorescent derivative. Employing bis(6-dansylaminohexyl)amine, the
Zhiming Zhang et al.
Inorganic chemistry, 47(17), 7615-7622 (2008-08-06)
The reaction between K 12[H 2P 2W 12O 48] and CuCl 2 in a NaCl aqueous solution assisted with organoamines (1,2-ethylenediamine (en), 1,6-hexamethylene diamine (hn), or both) leads to the isolation of three compounds: K 4Na 10[alpha 1-CuP 2W 17O
Linda G T Gaines et al.
Journal of environmental monitoring : JEM, 13(1), 119-127 (2010-10-28)
Although urinary 1,6-hexamethylene diamine (HDA) is a useful biomarker of exposure to 1,6-hexamethylene diisocyanate (HDI), a large degree of unexplained intra- and inter-individual variability exists between estimated HDI exposure and urine HDA levels. We investigated the effect of individual and
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