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Sigma-Aldrich

NovaSyn® TG carboxy resin

Novabiochem®

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About This Item

UNSPSC Code:
13111023

product line

NovaSyn® TG
Novabiochem®

form

beads

reaction suitability

reaction type: Fmoc solid-phase peptide synthesis

manufacturer/tradename

Novabiochem®

application(s)

peptide synthesis

storage temp.

2-30°C

General description

NovaSynTG carboxy resin is a composite of low cross-linked polystyrene and 3000-4000 M.W. polyethylene glycol, in which the ends of the PEG chains have been functionalized with carboxyl groups. The 130 μm beads have a narrow size distribution, high diffusion rates and excellent swelling properties across a wide range of solvents from toluene to water [1-3], making them ideally suited to the synthesis of serial and parallel libraries by organic solid phase synthesis.

This support can be used to immobilize alcohols through formation of an ester with the resin-bound carboxy group. Cleavage can be effected either by saponification, hydrazinolysis or reduction with LiBH4 .

In studies on the synthesis of furans via intramolecular radical cyclization, NovaSynTG carboxy resin was found to give superior results to carboxy polystyrene [4]. This observation was attributed to the notion that, in the PEG-based support, the radical intermediates would be prevented, by virtue of being tethered to the ends of PEG chains, from approaching and thus being quenched by the benzylic protons of the polystyrene backbone.

The product number for this product was previously 01-64-0097.

To obtain a certificate of analysis (CoA) of a lot that begins with the letter “A”, please select the option in the right hand menu “Request a COA for Lot#s starting with A”.

Linkage

Replaces: 01-64-0097

Analysis Note

Color (visual): white to yellow to beige
Appearance of substance (visual): beads
Loading (determined by elemental analysis of nitrogen after derivatization with methylamine): 0.30 - 0.60 mmol/g
Swelling Volume (in CH₂Cl₂): lot specific result
130 µm beads

Legal Information

NOVASYN is a registered trademark of Merck KGaA, Darmstadt, Germany
Novabiochem is a registered trademark of Merck KGaA, Darmstadt, Germany

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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