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E45708

Sigma-Aldrich

1-Ethylpiperidine

99%

Synonym(s):

N-Ethylpiperidine, NSC 2090

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100 ML
¥6,260
500 ML
¥19,200

¥6,260

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100 ML
¥6,260
500 ML
¥19,200

About This Item

Empirical Formula (Hill Notation):
C7H15N
CAS Number:
766-09-6
Molecular Weight:
113.20
Beilstein:
102643
EC Number:
212-161-6
MDL number:
MFCD00006507
UNSPSC Code:
12352100
PubChem Substance ID:
24894564
NACRES:
NA.22

¥6,260

In StockDetails

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Quality Level

100

Assay

99%

form

liquid

refractive index

n20/D 1.444 (lit.)

bp

131 °C (lit.)

density

0.824 g/mL at 25 °C (lit.)

SMILES string

CCN1CCCCC1

InChI

1S/C7H15N/c1-2-8-6-4-3-5-7-8/h2-7H2,1H3

InChI key

HTLZVHNRZJPSMI-UHFFFAOYSA-N

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Application

Reactant for:
Synthesis of multiprotected kanosamine[1]
Selective acylation in peptide synthesis[2]
Reagent for:
Stereoselective aldol condensation reactions for synthesis of β-lactam antibiotics[3]
Diastereoselective synthesis of aldols[4]
Crossed Claisen ester condensation[5]

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

62.6 °F

Flash Point(C)

17 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 1 petroleums
Hazardous rank II
Water insoluble liquid

JAN Code

E45708-5G:
E45708-100G:
E45708-VAR:
E45708-500ML:
E45708-BULK:
E45708-5ML:
E45708-500G:
E45708-100ML:

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Certificates of Analysis (COA)

Lot/Batch Number
STBK3640
STBH1127
STBC4731V
S85313
S60670V

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Laurence Miesch, et al
Synthesis, 1, 161-167 (2011)
Yoo Tanabe and Teruaki Mukaiyama
Chemistry Letters (Jpn), 11, 1813-1816 (1986)
Yoshimitsu Nagao, et al
Journal of the American Chemical Society, 20, 1418-1419 (1985)
Amino-acids and peptides. XXIV. The use of esters of 1-hydroxypiperidine and of other NN-dialkylhydroxylamines in peptide synthesis and as selective acylating agents.
B O Handford et al.
Journal of the Chemical Society. Perkin transactions 1, Dec, 6814-6827 (1965-12-01)
Mankil Jung and Marvin J. Miller
Tetrahedron Letters, 26, 977-980 (1985)
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