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CF0016

Sigma-Aldrich

4-Ethoxycarbonylphenoxytetrafluorobromoethane

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About This Item

Linear Formula:
C11H9BrF4O3
CAS Number:
896431-14-4
MDL number:
MFCD31546247
UNSPSC Code:
12352101

form

liquid

reaction suitability

reaction type: C-C Bond Formation

Application

4-Ethoxycarbonylphenoxytetrafluorobromoethane is a fluoroalkylbromide that is a radical source of the 4-ethoxycarbonylphenoxytetrafluoroethyl moiety. Alternatively, it can also be selectively metallated at the fluorinated carbon with Turbo Grignard reagent at low temperatures resulting in a thermally unstable anion that can act as a nucleophilic fluoroalkylation reagent towards a wide variety of electrophiles, such as aldehydes, ketones or sulfonylimines. The ester group can be transformed to other derivatives, building molecular complexity.

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Other Notes

Technology Spotlight: Fluoroalkylation: Expansion of Togni Reagents

Legal Information

Product of CF Plus Chemicals.

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

CF0016-1G:

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Certificates of Analysis (COA)

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Articles

Fluoroalkylation: Expansion of Togni Reagents

Fluoroalkylation toolbox expands with various reagents for late-stage fluoroalkylation in organic synthesis and medicinal chemistry.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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