Skip to Content
Merck
All Photos(1)

Documents

Safety Information

926116

Sigma-Aldrich

(R,R)-Ts-DENEB™

Synonym(s):

stereoisomer of Chloro[4-methyl-N-[(1R,2R)-2-[(S)-[2-[[(1,2,3,4,5,6-η)-4-methylphenyl]methoxy]ethyl]amino-κN]-1,2-diphenylethyl]benzenesulfonamidato-κN]ruthenium

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C31H33ClN2O3RuS
CAS Number:
1333981-84-2
Molecular Weight:
650.19
UNSPSC Code:
12161600
NACRES:
NA.22

form

powder

Quality Level

100

reaction suitability

reagent type: ligand

functional group

phosphine

Application

(R,R)-Ts-DENEB™ is an oxo-tethered ruthenium complex for use as an efficient asymmetric hydrogenation catalyst.

Other Notes

Oxo-Tethered Ruthenium(II) Complex as a Bifunctional Catalyst for Asymmetric Transfer Hydrogenation and H2 Hydrogenation

Legal Information

Product of Takasago.

For research and development purposes only. PCT/JP2011/064490
DENEB is a trademark of Takasago Intl. Corp.

related product

Product No.
Description
Pricing

926140

(S,S)-Ms-DENEB™

926132

(R,R)-Ms-DENEB™

926124

(S,S)-Ts-DENEB™

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

926116-250MG:
926116-1G:
926116-VAR:
926116-BULK:
926116-5G:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Taichiro Touge et al.
Journal of the American Chemical Society, 133(38), 14960-14963 (2011-08-30)
Newly developed oxo-tethered Ru amido complexes (R,R)-1 and their HCl adducts (R,R)-2 exhibited excellent catalytic performance for both asymmetric transfer hydrogenation and the hydrogenation of ketonic substrates under neutral conditions without any cocatalysts to give chiral secondary alcohols with high

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service