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Safety Information

918997

Sigma-Aldrich

AndrewPhos

≥95%

Synonym(s):

14,14-Dimethyl-13-(3-methoxy-2′,4′,6′-triisopropyl-[1,1′-biphenyl]-2-yl)-1,4-dioxa-13-phosphadispiro[4.1.5.3]pentadecane

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50 MG
¥49,500
250 MG
¥154,000

¥49,500


Estimated to ship onJune 02, 2025


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50 MG
¥49,500
250 MG
¥154,000

About This Item

Empirical Formula (Hill Notation):
C36H53O3P
CAS Number:
Molecular Weight:
564.78
MDL number:
UNSPSC Code:
12352112
NACRES:
NA.22

¥49,500


Estimated to ship onJune 02, 2025


Request a Bulk Order

Quality Level

Assay

≥95%

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

reagent type: ligand

functional group

phosphine

storage temp.

−20°C

SMILES string

P3(C4(CC5(OCCO5)CC3(C)C)CCCCC4)c1c(cccc1c2c(cc(cc2C(C)C)C(C)C)C(C)C)OC

InChI key

CNDZLFAQJZQSQK-UHFFFAOYSA-N

Application

AndrewPhos is a biaryl phosphorinane ligand for Pd catalysis. This ligand has been used in a variety of Pd-catalyzed reactions including the sulfonamidation of aryl halides, C-O couplings, and C-N couplings.

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Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

918997-50MG:
918997-VAR:
918997-BULK:
918997-250MG:


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Pd-Catalyzed Cross-Coupling Reactions Promoted by Biaryl Phosphorinane Ligands.
Laffoon S D, et al.
ACS Catalysis, 9(12), 11691-11708 (2019)

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