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918105

Sigma-Aldrich

(MeBPI)2Ni

≥95%

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250 MG
¥18,700
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¥50,300

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250 MG
¥18,700
1 G
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About This Item

Empirical Formula (Hill Notation):
C40H32N10Ni
CAS Number:
78065-33-5
Molecular Weight:
711.44
MDL number:
MFCD33021718
UNSPSC Code:
12352103
NACRES:
NA.22

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Quality Level

100

Assay

≥95%

form

crystals

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

SMILES string

[Ni+2].[N-]5\C(=N\c8nccc(c8)C)\c6c(cccc6)\C\5=N/c7nccc(c7)C.[N-]1\C(=N\c4nccc(c4)C)\c2c(cccc2)\C\1=N/c3nccc(c3)C

InChI key

UEBWUPHCLCWDLU-UHFFFAOYSA-N

Related Categories

Application

(MeBPI)2Ni is a redox-active shuttle developed in the Sevov lab for electrocatalytic cross-electrophile coupling reactions. When combined with (MeBPI)Ni-OAc (919365), (MeBPI)Ni-OAc enables the reductive coupling of a wide range of aryl, heteroaryl, or vinyl bromides with primary or secondary alkyl bromides.

Product can be used with our Synlectro electrochemistry platform (ESYNTH001)

Other Notes

General C(sp2)-C(sp3) Cross-Electrophile Coupling Reactions Enabled by Overcharge Protection of Homogeneous Electrocatalysts

related product

Product No.
Description
Pricing

919365

(MeBPI)Ni-OAc

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

918105-VAR:
918105-BULK:
918105-250MG:4548173370101
918105-1G:4548173370095

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Blaise L Truesdell et al.
Journal of the American Chemical Society, 142(12), 5884-5893 (2020-03-03)
Cross-electrophile coupling (XEC) of alkyl and aryl halides promoted by electrochemistry represents an attractive alternative to conventional methods that require stoichiometric quantities of high-energy reductants. Most importantly, electroreduction can readily exceed the reducing potentials of chemical reductants to activate catalysts

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