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913758

Sigma-Aldrich

Phen-NaDPO

Synonym(s):

3-[6-(diphenylphosphinyl)-2-naphthalenyl]-1,10-Phenanthroline

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About This Item

Empirical Formula (Hill Notation):
C34H23N2OP
CAS Number:
1480371-38-7
Molecular Weight:
506.53
MDL number:
MFCD31811570
UNSPSC Code:
12352103
NACRES:
NA.23

Assay

≥98%

Quality Level

100

form

powder

transition temp

Tg ~116 °C

solubility

soluble (Soluble in polar and weakly polar solvents such as isopropanol, toluene and xylenes)

semiconductor properties

(mobility=0.0001-0.001 cm2/V·s) (electron)

Application

Phen-NaDPO is a universal cathode modifier for organic optoelectronics. Phen-NaDPO can significantly lower the work function of the Ag metal as well as ITO and HOPG.
It lowers the energy loss between organic layer and the metal electrode, results in higher acheiveable efficiency for organic solar cells. It is also used as cathode interfacial material for inverted Perovskite solar cells, and electron transport materials for Perovskite solar cells and other organic electronic devices in general.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

913758-BULK:
913758-100MG:
913758-VAR:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Triarylphosphine Oxide as Cathode Interfacial Material for Inverted Perovskite Solar Cells.
Wang K, et al.
Advanced Materials Interfaces, 6(12) (2019)
Tuning of the conformation of asymmetric nonfullerene acceptors for efficient organic solar cells.
Yang L,et al.
Journal of Material Chemistry A, 7(39), 22279-22286 (2019)
Use of the Phen-NaDPO:Sn(SCN)2 Blend as Electron Transport Layer Results to Consistent Efficiency Improvements in Organic and Hybrid Perovskite Solar Cells.
Seitkhan A, et al.
Advances in Functional Materials, 29(49), 1905810-1905810 (2019)
Improved quantum dot light-emitting diodes with a cathode interfacial layer.
Ding T, et al.
Organic Electronics, 32, 89-93 (2016)
Qiang Su et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 5(10), 1800549-1800549 (2018-10-26)
The phenomenon of positive aging, i.e., efficiency increased with time, is observed in quantum-dot light-emitting diodes (QLEDs). For example, the external quantum efficiency (EQE) of blue QLEDs is significantly improved from 4.93% to 12.97% after storage for 8 d. The

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