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Safety Information

908193

Sigma-Aldrich

3CzClIPN

Synonym(s):

2,4,6-Tri(9H-carbazol-9-yl)-5-chloroisophthalonitrile

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About This Item

Empirical Formula (Hill Notation):
C44H24ClN5
CAS Number:
1469704-61-7
Molecular Weight:
658.15
UNSPSC Code:
12352101
NACRES:
NA.22

form

powder or crystals

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

mp

>300 °C

Application

3CzClIPN is cyanoarene-based donor-acceptor photocatalyst developed by the Zeitler group. While this catalyst has a balanced redox profile, allowing for its use in a variety of transformations, it stands out as the most oxidizing catalyst of the family.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

A Toolbox Approach To Construct Broadly Applicable Metal-Free Catalysts for Photoredox Chemistry: Deliberate Tuning of Redox Potentials and Importance of Halogens in Donor-Acceptor Cyanoarenes

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926795

3CzEPAIPN, ≥95%

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

JAN Code

908193-500MG:
908193-100MG:
908193-BULK:
908193-VAR:

Certificates of Analysis (COA)

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Elisabeth Speckmeier et al.
Journal of the American Chemical Society, 140(45), 15353-15365 (2018-10-03)
The targeted choice of specific photocatalysts has been shown to play a critical role for the successful realization of challenging photoredox catalytic transformations. Herein, we demonstrate the successful implementation of a rational design strategy for a series of deliberate structural

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