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904104

Sigma-Aldrich

CoCl2(PCy3)2

Synonym(s):

Dichlorobis(tricyclohexylphosphine)cobalt(II)

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250 MG
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250 MG
¥15,000

About This Item

Empirical Formula (Hill Notation):
C36H66Cl2CoP2
CAS Number:
14726-62-6
Molecular Weight:
690.70
MDL number:
MFCD31807340
UNSPSC Code:
12352101
NACRES:
NA.22

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form

powder or crystals

reaction suitability

core: cobalt
reagent type: catalyst

mp

>300 °C

SMILES string

[Co](Cl)Cl.P(C6CCCCC6)(C5CCCCC5)C4CCCCC4.P(C3CCCCC3)(C2CCCCC2)C1CCCCC1

InChI

1S/2C18H33P.2ClH.Co/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*16-18H,1-15H2;2*1H;/q;;;;+2/p-2

InChI key

XTBDMUPZCVAWRK-UHFFFAOYSA-L

Related Categories

Application

This cobalt catalyst can be used in conjunction with the photocatalyst (Ir[dF(CF3)ppy]2(dtbpy))PF6(747793) for the [2+2+2] alkyne cycloaddition.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Visible light-gated cobalt catalysis for a spatially and temporally resolved [2+2+2] cycloaddition

related product

Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

904104-1G:
904104-250MG:
904104-BULK:
904104-VAR:

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Kyle E Ruhl et al.
Journal of the American Chemical Society, 138(48), 15527-15530 (2016-12-10)
The ability to exert spatial and temporal control over a transition-metal catalyst offers diverse opportunities for the fabrication of functional materials. Using an external stimulus such as visible light to toggle a catalyst between an active and dormant state has

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