748811

Allyl 1H-imidazole-1-carboxylate

95%

• Synonym(s): Heller-Sarpong Reagent, Allyl imidazolecarbamate, AllylImC, Imidazole-1-carboxylic acid 2-propen-1-yl ester, Sarpong reagent
• Empirical Formula (Hill Notation): C₇H₈N₂O₂
• CAS Number: 83395-39-5
• Molecular Weight: 152.15
• MDL number: MFCD18835431
• UNSPSC Code: 12352005
• PubChem Substance ID: 329765935
• NACRES: NA.22
• form: liquid
• Assay: 95%

Properties

• Assay: 95%
• form: liquid
• refractive index: n20/D 1.494
• density: 1.146 g/mL at 25 °C
• shipped in: wet ice
• storage temp.: 2-8°C
• SMILES string: C=CCOC(=O)n1ccnc1
• InChI: 1S/C7H8N2O2/c1-2-5-11-7(10)9-4-3-8-6-9/h2-4,6H,1,5H2
• InChI key: NEFLGCHXJFBCQP-UHFFFAOYSA-N

Description

General description

Allyl 1H-imidazole-1-carboxylate is an organic reagent used to introduce carboxyallyl groups to nucleophilic nitrogen, oxygen, and carbon centers. It is used in the acylation reactions of enolates and nitrogen compounds. Further, it can also be used in the synthesis of carbonates and allyl esters.

Application

Allyl 1H-imidazole-1-carboxylate can be used:

• To prepare allyl enol carbonate derivatives by reacting with ketone enolates and boron trifluoride etherate.
• In the acylation of a mixture of primary and secondary alcohols.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H302,H315,H319,H335
• Precautionary Statements: P261 - P264 - P270 - P301 + P312 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable