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743569

Sigma-Aldrich

Bis[(10,11-η)-5-[(11bS)-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl- κP4]-5H-dibenz[b,f]azepine]rhodium(I) tetrafluoroborate salt

97%

Synonym(s):

Bis[(10,11-η)-(S)-N-[(3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4-a′]dinaphthalen-4-yl-κP4)]-dibenzo[b,f]azepine]rhodium(I) tetrafluoroborate salt

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About This Item

Empirical Formula (Hill Notation):
C68H44BF4N2O4P2Rh
CAS Number:
1228149-03-8
Molecular Weight:
1204.75
MDL number:
MFCD22417199
UNSPSC Code:
12352300
PubChem Substance ID:
329765640
NACRES:
NA.22

Assay

≥97% (elemental analysis)
97%

composition

carbon content, 68.42-70.16%

reaction suitability

core: rhodium
reagent type: catalyst

SMILES string

[Rh+].F[B-](F)(F)F.O1P(Oc2ccc3ccccc3c2-c4c1ccc5ccccc45)N6c7ccccc7C=Cc8ccccc68.O9P(Oc%10ccc%11ccccc%11c%10-c%12c9ccc%13ccccc%12%13)N%14c%15ccccc%15C=Cc%16ccccc%14%16

InChI

1S/2C34H22NO2P.BF4.Rh/c2*1-5-13-27-23(9-1)19-21-31-33(27)34-28-14-6-2-10-24(28)20-22-32(34)37-38(36-31)35-29-15-7-3-11-25(29)17-18-26-12-4-8-16-30(26)35;2-1(3,4)5;/h2*1-22H;;/q;;-1;+1

InChI key

RFMQVNMFBNKHLB-UHFFFAOYSA-N

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Analysis Note

contains ~10% ether and 5% THF

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

JAN Code

743569-BULK:
743569-100MG:4548173910994
743569-VAR:

Certificates of Analysis (COA)

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