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723320

Sigma-Aldrich

Magnesium

in a Sure/Seal™ bottle, turnings, anhydrous tetrahydrofuran 37.5 mmol

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About This Item

Empirical Formula (Hill Notation):
Mg
CAS Number:
7439-95-4
Molecular Weight:
24.31
Beilstein:
4948473
MDL number:
MFCD00085308
UNSPSC Code:
12352300
PubChem Substance ID:
329763997
NACRES:
NA.22

vapor pressure

1 mmHg ( 621 °C)

form

turnings

autoignition temp.

950 °F

composition

anhydrous tetrahydrofuran, 37.5 mmol

reaction suitability

reagent type: reductant

resistivity

4.46 μΩ-cm, 20°C

bp

1090 °C (lit.)

mp

648 °C (lit.)

density

1.74 g/mL at 25 °C (lit.)

SMILES string

[Mg]

InChI

1S/Mg

InChI key

FYYHWMGAXLPEAU-UHFFFAOYSA-N

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Application

Magnesium turnings (Mg) can be used to prepare reactive organomagnesium compounds (Grignard reagents, GR) by reacting with alkyl, allyl, vinyl, or aryl halides. These GR reagents are widely used in organic synthesis to produce useful chemical intermediates. Mg can also be used to prepare tetraisopropyl- and tetrabutyl-distibane by dehalogenation of diisopropyl- and dibutyl-antinomy bromide, respectively.

Other Notes

Based on preparing 0.5 M solution of organomagnesium reagent and 40% headspace.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Self-heat. 1 - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH018,EUH019

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 1

Flash Point(F)

1.4 °F - closed cup

Flash Point(C)

-17.0 °C - closed cup

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 3: Spontaneously combustible substances and water- reactive materials
Materials containing Alkali metals (except potassium and sodium) and alkaline earth metals
Hazardous rank I
1st spontaneously combustible materials and water reactive materials

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

723320-BULK:
723320-VAR:
723320-75ML:4548173983462

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Reduktion von isopropyl-und butylantimonbromiden mit magnesium
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