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Safety Information

71290

Sigma-Aldrich

Sodium azide

purum p.a., ≥99.0% (T)

Synonym(s):

Hydrazoic acid sodium salt, NSC 3072

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10 G
¥5,160
100 G
¥14,000
500 G
¥35,000

About This Item

Linear Formula:
NaN3
CAS Number:
Molecular Weight:
65.01
EC Number:
MDL number:
UNSPSC Code:
12352201
PubChem Substance ID:
NACRES:
NA.21
Assay:
≥99.0% (T)
form:
crystals
solubility:
H2O: 0.1 g/mL, clear, colorless

¥5,160


Estimated to ship onApril 02, 2025


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grade

purum p.a.

Quality Level

Assay

≥99.0% (T)

form

crystals

solubility

H2O: 0.1 g/mL, clear, colorless

anion traces

chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤50 mg/kg
Cd: ≤50 mg/kg
Co: ≤50 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
K: ≤100 mg/kg
Ni: ≤50 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg

SMILES string

[Na]N=[N+]=[N-]

InChI

1S/N3.Na/c1-3-2;/q-1;+1

InChI key

PXIPVTKHYLBLMZ-UHFFFAOYSA-N

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Application

Catalyst for:
  • Oxidative decarboxylation[1]
  • Michael addition reactions[2]

Reagent for synthesis of
  • Blue fluorescent copolymers[3]
  • Metal phosphonates[4]
  • Arenes via aminations[5]

Involved in regioselective synthesis of prianosin B[6]

Other Notes

Schmidt reaction with aldehydes and carboxylic acids, a review[7]

suggested gloves for splash protection

Signal Word

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2 Oral

Target Organs

Brain

Supplementary Hazards

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Poisonous substance

FSL

Group 5: Self-reactive substances
Metal azides
Hazardous rank II
2nd self-reactive materials

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

71290-500G:4548173178172
71290-RSAMPLE:
71290-100G:4548173178158
71290-6X500G:4548173272795
71290-6X100G:4548173272788
71290-10G:4548173178165
71290-VAR:
71290-BULK:


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G.I. Koldobski et al.
Russ. Chem. Rev., 47, 1084-1084 (1978)
H. Chen, et al.,
Macromolecules, 43, 3613-3623 (2010)
Xiaohua Sun et al.
Organic letters, 9(22), 4495-4498 (2007-10-04)
A novel intermolecular cross-double-Michael addition between nitro and carbonyl activated olefins has been developed through Lewis base catalysis. The reaction took place with a large group of beta-alkyl nitroalkenes and alpha,beta-unsaturated ketone/esters, producing an allylic nitro compound in good to
Y. Wada, et al.,
Tetrahedron, 65, 1059-1062 (2009)
Deng-Ke Cao et al.
Inorganic chemistry, 44(10), 3599-3604 (2005-05-10)
Based on the [hydroxy(4-pyridyl)methyl]phosphonate ligand, three compounds with formula Ni{(4-C(5)H(4)N)CH(OH)PO(3)}(H(2)O) (1), Cd{(4-C(5)H(4)N)CH(OH)PO(3)}(H(2)O) (2), and Gd{(4-C(5)H(4)N)CH(OH)P(OH)O(2)}(3).6H(2)O (3) have been synthesized under hydrothermal conditions. The crystal data for 1 are as follows: orthorhombic, space group Pbca, a = 8.7980(13) A, b =

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