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Safety Information

710180

Sigma-Aldrich

Di-2-methoxyethyl azodicarboxylate

≥90.0%

Synonym(s):

Azodicarboxylic acid bis(2-methoxyethyl ester), DMEAD

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About This Item

Empirical Formula (Hill Notation):
C8H14N2O6
CAS Number:
940868-64-4
Molecular Weight:
234.21
Beilstein:
11134057
MDL number:
MFCD17018843
UNSPSC Code:
12352108
PubChem Substance ID:
329762905
NACRES:
NA.22

Assay

≥90.0%

form

crystals

functional group

azo
ether

storage temp.

2-8°C

SMILES string

COCCOC(=O)\N=N\C(=O)OCCOC

InChI

1S/C8H14N2O6/c1-13-3-5-15-7(11)9-10-8(12)16-6-4-14-2/h3-6H2,1-2H3/b10-9+

InChI key

PGHKJMVOHWKSLJ-MDZDMXLPSA-N

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Danger

Hazard Statements

H242,H315,H319,H332,H335

Hazard Classifications

Acute Tox. 4 Inhalation - Eye Irrit. 2 - Self-react. D - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 5: Self-reactive substances
Azo compounds
Hazardous rank II
2nd self-reactive materials

JAN Code

710180-BULK:
710180-25G:
710180-5G:
710180-VAR:
710180-1G:

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Certificates of Analysis (COA)

Lot/Batch Number
BCCC5328
BCCB8492
BCBZ4611
BCBV9335
BCBR2977V

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Di-2-methoxyethyl azodicarboxylate (DMEAD): an inexpensive and separation-friendly alternative reagent for the Mitsunobu reaction.
Sugimura, T. and Hagiya, K.
Chemistry Letters (Jpn), 36, 566-567 (2007)

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