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708763

Sigma-Aldrich

[(S)-(−)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride

Synonym(s):

[PdCl2{(S)-4-tolylbinap}]

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About This Item

Empirical Formula (Hill Notation):
C48H40Cl2P2Pd
CAS Number:
215597-19-6
Molecular Weight:
856.10
MDL number:
MFCD11656205
UNSPSC Code:
12352005
PubChem Substance ID:
329762823

form

solid

mp

>300 °C

functional group

phosphine

SMILES string

Cl[Pd]Cl.Cc1ccc(cc1)P(c2ccc(C)cc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccc(C)cc7)c8ccc(C)cc8

InChI

1S/C48H40P2.2ClH.Pd/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;;;/h5-32H,1-4H3;2*1H;/q;;;+2/p-2

InChI key

ADMKISPNGKUJAU-UHFFFAOYSA-L

Application

Catalyst for:
  • Stereoselective preparation of hydroxymethyldihydronaphthalenone via alkylative ring opening of oxabenzonorbornadiene with (PhMe2SiCH2)2Zn followed by hydrogenation and Tamao-Fleming oxidation
  • Asymmetric synthesis of cyclopentylindanes via cyclization of bromo- and trifluoromethanesulfonyloxyphenylheptenylmalonate

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

708763-BULK:
708763-VAR:
708763-100MG:
708763-500MG:

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Certificates of Analysis (COA)

Lot/Batch Number
14496CK

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