708518
1,3-Bis(diphenylphosphinomethyl)benzene
Synonym(s):
α,α′-Bis(diphenylphosphino)-m-xylene, [1,3-Phenylenebis(methylene)]bis[diphenyl]phosphine
About This Item
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form
powder
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
mp
50-55 °C
functional group
phosphine
SMILES string
C(P(c1ccccc1)c2ccccc2)c3cccc(CP(c4ccccc4)c5ccccc5)c3
InChI
1S/C32H28P2/c1-5-16-29(17-6-1)33(30-18-7-2-8-19-30)25-27-14-13-15-28(24-27)26-34(31-20-9-3-10-21-31)32-22-11-4-12-23-32/h1-24H,25-26H2
InChI key
QLSOZHFOFHARBJ-UHFFFAOYSA-N
Application
- Cyclometalation of pincer ligands
- Insertion of carbon dioxide into (PCP)PDII-Me Bonds
- Synthesis of iridium complexes containing bidentate phosphine ligands
- Transcyclometalation processes
- Synthesis of vinylidene and carbyne complexes
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Chronic 4
Storage Class Code
13 - Non Combustible Solids
WGK
WGK 3
Flash Point(F)
>230.0 °F
Flash Point(C)
> 110 °C
Regulatory Listings
Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.
JAN Code
708518-BULK:
708518-VAR:
708518-1G:
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