703486
sec-Butylmagnesium chloride lithium chloride complex solution
1.2 M in THF
Synonym(s):
2-Butylmagnesium chloride lithium chloride complex, Turbo Grignard
About This Item
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form
liquid
reaction suitability
reaction type: Grignard Reaction
concentration
1.2 M in THF
14 % (w/w)
density
0.973 g/mL at 25 °C
SMILES string
[Li]Cl.CCC(C)[Mg]Cl
InChI
1S/C4H9.2ClH.Li.Mg/c1-3-4-2;;;;/h3H,4H2,1-2H3;2*1H;;/q;;;2*+1/p-2
InChI key
ZMDHAYOBNXOYEU-UHFFFAOYSA-L
Application
Legal Information
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
Target Organs
Central nervous system, Respiratory system
Supplementary Hazards
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 1
Flash Point(F)
-6.7 °F
Flash Point(C)
-21.5 °C
Personal Protective Equipment
Regulatory Listings
Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.
PRTR
Class I Designated Chemical Substances
FSL
Group 3: Spontaneously combustible substances and water- reactive materials
Materials containing Organometallic compounds
Hazardous rank I
1st spontaneously combustible materials and water reactive materials
ISHL Indicated Name
Substances Subject to be Indicated Names
ISHL Notified Names
Substances Subject to be Notified Names
JAN Code
703486-100ML:4548173298016
703486-800ML:4548173298023
703486-BULK:
703486-VAR:
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Articles
Salt additives increase both the rate and the efficiency of the Mg-halogen exchange reaction. The most effective reagents are generated with R-MgCl (R = i-Pr, s-Butyl) and 1.0 equiv of LiCl.
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