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701769

Sigma-Aldrich

Dichloro(mesitylene)ruthenium(II) dimer

95%

Synonym(s):

(Mesitylene)dichlororuthenium dimer, Bis[dichloro(mesityl)ruthenium], Tetrachlorobis(mesitylene)diruthenium;, [RuCl2(mesitylene)]2, Di-μ-chlorodichlorobis[(1,2,3,4,5,6-η)-1,3,5-trimethylbenzene]diruthenium, Ruthenium(II) chloride mesitylene dimer

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About This Item

Empirical Formula (Hill Notation):
C18H24Cl4Ru2
CAS Number:
52462-31-4
Molecular Weight:
584.34
UNSPSC Code:
12161600
PubChem Substance ID:
329762318
NACRES:
NA.22

Assay

95%

form

crystals

reaction suitability

core: ruthenium
reagent type: catalyst

mp

>300 °C

storage temp.

2-8°C

SMILES string

Cl[Ru]1[Cl][Ru](Cl)[Cl]1.C[C]2[CH][C](C)[CH][C](C)[CH]2.C[C]3[CH][C](C)[CH][C](C)[CH]3

InChI

1S/2C9H12.2ClH.2Cl.2Ru/c2*1-7-4-8(2)6-9(3)5-7;;;;;;/h2*4-6H,1-3H3;2*1H;;;;/q;;;;;;2*+1/p-2

InChI key

SQSMPOQPOXFKBI-UHFFFAOYSA-L

Application

Catalyst for asymmetric hydrogenation, transfer hydrogenation, Diels-Alder reaction

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H319

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

701769-BULK:
701769-500MG:
701769-100MG:
701769-VAR:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Davies, D. L.; Fawcett, J. et al.
Chemical Communications (Cambridge, England), 3151-3151 (1997)
Damjan Sterk et al.
Organic letters, 8(26), 5935-5938 (2006-12-15)
[Structure: see text] The asymmetric transfer hydrogenation of fluoroalkyl ketones mediated by [Ru(eta6-arene)((S,S)-R2NSO2DPEN)] catalysts using HCO2H-Et3N afforded the corresponding alcohols with high ee's and in excellent yields.

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