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692409

Sigma-Aldrich

(R)−RuCl[(p−cymene)(DM−BINAP)]Cl

Synonym(s):

Chloro[(R)−(+)−2,2′−bis(di−(3,5−xylyl)phosphino)−1,1′−binaphthyl](p−cymene)ruthenium(II) chloride

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About This Item

Linear Formula:
[C62H62ClP2Ru]+Cl−
CAS Number:
944451-24-5
Molecular Weight:
1041.08
UNSPSC Code:
12352101
PubChem Substance ID:
329761492
NACRES:
NA.22

form

powder

storage temp.

2-8°C

SMILES string

[Cl-].Cl[Ru+].C[C]1[CH][CH][C]([CH][CH]1)C(C)C.Cc2cc(C)cc(c2)P(c3cc(C)cc(C)c3)c4ccc5ccccc5c4-c6c(ccc7ccccc67)P(c8cc(C)cc(C)c8)c9cc(C)cc(C)c9

InChI

1S/C52H48P2.C10H14.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-8(2)10-6-4-9(3)5-7-10;;;/h9-32H,1-8H3;4-8H,1-3H3;2*1H;/q;;;;+2/p-2

InChI key

CBZXDZCPCDMKJU-UHFFFAOYSA-L

Related Categories

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

Sold in collaboration with Takasago for research purposes only.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

692409-50MG:
692409-BULK:
692409-VAR:
692409-100MG:

Certificates of Analysis (COA)

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Articles

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

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