Skip to Content
Merck
All Photos(3)

Key Documents

View All Documentation

Safety Information

683175

Sigma-Aldrich

Chiralyst P374

Umicore

Synonym(s):

Bis(norbornadiene)rhodium(I) tetrafluoroborate, Bis(bicyclo[2.2.1]hepta-2,5-diene)rhodium tetrafluoroborate, Bis(norbornadiene)(tetrafluoroborato)rhodium, Rh(nbd)2BF4, Rh(nbd)2BF4

Sign Into View Organizational & Contract Pricing

Select a Size

500 MG
¥41,700
2 G
¥118,000

¥41,700

Available to ship onApril 11, 2025Details

Request a Bulk Order
All Photos(3)

Select a Size

Change View
500 MG
¥41,700
2 G
¥118,000

About This Item

Linear Formula:
[Rh(NBD)BF4
CAS Number:
36620-11-8
Molecular Weight:
373.99
MDL number:
MFCD00671775
UNSPSC Code:
12161600
PubChem Substance ID:
329760802
NACRES:
NA.22

¥41,700

Available to ship onApril 11, 2025Details

Request a Bulk Order

form

solid

reaction suitability

core: rhodium
reagent type: catalyst

mp

136.9-139.9 °C

SMILES string

[Rh+].F[B-](F)(F)F.C1C2C=CC1C=C2.C3C4C=CC3C=C4

InChI

1S/2C7H8.BF4.Rh/c2*1-2-7-4-3-6(1)5-7;2-1(3,4)5;/h2*1-4,6-7H,5H2;;/q;;-1;+1/t2*6-,7+;;

InChI key

HAYDJWBQWOEERB-JAGGYEKFSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
Bis(norbornadiene)rhodium(I) tetrafluoroborate can be used as a catalyst for the synthesis of:
  • Lactones via the 1,4-addition of arylboronic acids to butenolide.[1]
  • Chiral β-aryl-substituted ketones and esters.[2]
  • β-aryloxycarboxylic esters from β-aryloxy-α,γ-unsaturated esters.[3]

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

PRTR

Class I Designated Chemical Substances

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

683175-500MG:4548173287331
683175-BULK:
683175-2G:4548173287348
683175-VAR:

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCW0658
MKCT0598
MKCT8854
MKCQ4592
MKCP0923

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Articles

Umicore Precatalysts

Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.

Questions

Reviews

No rating value

Active Filters

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service