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Safety Information

675571

Sigma-Aldrich

1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate

≥97%

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About This Item

Empirical Formula (Hill Notation):
C27H40F3O3P2RhS
CAS Number:
187682-63-9
Molecular Weight:
666.52
MDL number:
MFCD00269862
UNSPSC Code:
12352005
PubChem Substance ID:
24885289

Assay

≥97%

form

solid

SMILES string

[Rh+].[O-]S(=O)(=O)C(F)(F)F.C1CC=CCCC=C1.C[C@@H]2CC[C@@H](C)P2c3ccccc3P4[C@H](C)CC[C@H]4C

InChI

1S/C18H28P2.C8H12.CHF3O3S.Rh/c1-13-9-10-14(2)19(13)17-7-5-6-8-18(17)20-15(3)11-12-16(20)4;1-2-4-6-8-7-5-3-1;2-1(3,4)8(5,6)7;/h5-8,13-16H,9-12H2,1-4H3;1-2,7-8H,3-6H2;(H,5,6,7);/q;;;+1/p-1/b;2-1-,8-7-;;/t13-,14-,15-,16-;;;/m1.../s1

InChI key

AKJDLXZYNLUJQJ-MYDVBLLJSA-M

Application

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Legal Information

Sold in collaboration with Kanata Chemical Technologies Inc. for research purposes only. These compounds were made and sold under license from E.I. du Pont de Nemours and Company, which license does not include the right to use the compounds in producing products for sale in the pharmaceutical field.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

675571-VAR:
675571-BULK:
675571-100MG:
675571-500MG-PW:
675571-500MG:
675571-100MG-PW:

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Certificates of Analysis (COA)

Lot/Batch Number
12367AH
12267AH
06104KE

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Articles

DuPhos and BPE Ligands

Asymmetric hydrogenation enables scalable synthesis of single-enantiomer compounds with minimal byproducts, ideal for commercial manufacturing.

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