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667242

Sigma-Aldrich

Chloro(indenyl)bis(triphenylphosphine)ruthenium(II)

may contain ≤1 molar equivalent dichloromethane/acetone

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About This Item

Linear Formula:
C9H7 · RuCl · 2(C18H15P)
CAS Number:
99897-61-7
Molecular Weight:
776.25
MDL number:
MFCD01073793
UNSPSC Code:
12352300
PubChem Substance ID:
24884897

form

solid

reaction suitability

core: ruthenium
reagent type: catalyst

impurities

may contain ≤1 molar equivalent dichloromethane/acetone

SMILES string

Cl[Ru].[CH]1[CH][C]2C=CC=C[C]2[CH]1.c3ccc(cc3)P(c4ccccc4)c5ccccc5.c6ccc(cc6)P(c7ccccc7)c8ccccc8

InChI

1S/2C18H15P.C9H7.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-5-9-7-3-6-8(9)4-1;;/h2*1-15H;1-7H;1H;/q;;;;+1/p-1

InChI key

AUSVTIHCDLKYHV-UHFFFAOYSA-M

Application

Catalyst for olefination of carbonyl compounds.[1] Catalyst precursor for living radical polymerization.[2] Catalyst for redox isomerization of propargylic alcohols.[3]
Catalyst for:
  • Single-chain folding of polymers
  • Domino redox bicycloisomerization
  • Selective radical addition with a designed heterobifunctional halide
  • Tandem living radical polymerization via in situ monomer transformation with alcohols
  • Atom-economical synthesis of nitrogen heterocycles

Reactant for the synthesis of chiral-at-metal ruthenium allenylidene complexes

Pictograms

Health hazardExclamation mark
GHS08,GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H351

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

667242-BULK:
667242-5G:
667242-VAR:
667242-1G:4548174002476

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Certificates of Analysis (COA)

Lot/Batch Number
MKBW8366V
MKBV8687V
MKBN2332V
MKBD1353V
MKBD1353

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Pedro et al.
Organometallics, 26, 302-302 (2007)
Lizuka et al.
European Journal of Organic Chemistry, 782-782 (2007)
Trost, B.M. et al.
Journal of the American Chemical Society, ASAP-ASAP (2008)

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