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Sigma-Aldrich

Pd EnCat® Kit I

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About This Item

UNSPSC Code:
12352300
NACRES:
NA.22

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

Application

Catalysis Screening Kits

A kit of 5 Pd EnCat® catalysts which are micro-encapsulated palladium acetate catalysts with or without phosphine ligands which facilitate carbon-carbon bond forming processes as well as the removal of palladium metal contamination.

Legal Information

EnCat is a registered trademark of Reaxa Ltd.

Kit Components Also Available Separately

Product No.
Description
SDS
  • 644692Pd EnCat® TOTP30, extent of labeling: 0.4 mmol/g Pd loading, TOTP 0.5, Pd 1.0 1 gSDS
  • 644706Pd EnCat® TPP30, extent of labeling: 0.4 mmol/g Pd loading, TPP 0.8, Pd 1.0 1 gSDS
  • 644714Pd EnCat® 30, extent of labeling: 0.4 mmol/g Pd loading 1 gSDS
  • 644722Pd EnCat® 40, extent of labeling: 0.4 mmol/g Pd loading 1 gSDS
  • 658693Pd(II) EnCat® BINAP30, extent of labeling: 0.39 mmol/g Pd loading, BINAP 0.25, Pd 1.0 1 gSDS

Signal Word

Danger

Hazard Classifications

Aquatic Chronic 3 - Carc. 2 - Eye Irrit. 2 - Flam. Sol. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 2 Inhalation - STOT RE 2 Oral

Target Organs

Liver,Kidney, Nervous system

Storage Class Code

4.1B - Flammable solid hazardous materials

Flash Point(F)

-9.4 - -7.6 °F

Flash Point(C)

-23 - -22 °C

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Please refer to KIT Component information

PRTR

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FSL

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ISHL Indicated Name

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ISHL Notified Names

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Cartagena Act

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JAN Code

キットコンポーネントの情報を参照してください

Certificates of Analysis (COA)

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Jin-Quan Yu et al.
Chemical communications (Cambridge, England), (6), 678-679 (2003-04-22)
A robust and recyclable palladium catalyst [Pd0EnCat] has been prepared by ligand exchange of polyurea-encapsulated palladium(II) acetate with formic acid, resulting in deposition of Pd(0) in the support material; Pd0EnCat is shown to be a highly efficient transfer hydrogenation catalyst
Steven V Ley et al.
Organic letters, 5(24), 4665-4668 (2003-11-25)
[reaction: see text] Pd nanoparticles (approximately 2 nm in size) microencapsulated in polyurea is an efficient and recyclable catalyst for reductive ring-opening hydrogenolysis of epoxides, using either HCOOH/Et(3)N or H(2) as a hydrogen donor.

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