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666181

Sigma-Aldrich

1,3-Dicyclohexylimidazolium tetrafluoroborate salt

97%

Synonym(s):

1,3-Bis(cyclohexyl)imidazolium tetrafluoroborate

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5 G
¥38,700

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5 G
¥38,700

About This Item

Empirical Formula (Hill Notation):
C15H25BF4N2
CAS Number:
286014-38-8
Molecular Weight:
320.18
MDL number:
MFCD04973310
UNSPSC Code:
12352005
PubChem Substance ID:
24884784
NACRES:
NA.22

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Assay

97%

form

solid

reaction suitability

reagent type: catalyst

mp

171-175 °C

SMILES string

F[B-](F)(F)F.C1CCC(CC1)n2cc[n+](c2)C3CCCCC3

InChI

1S/C15H25N2.BF4/c1-3-7-14(8-4-1)16-11-12-17(13-16)15-9-5-2-6-10-15;2-1(3,4)5/h11-15H,1-10H2;/q+1;-1

InChI key

CQHXJIHJFMBBQA-UHFFFAOYSA-N

Related Categories

Application

Used as organocatalyst in the catalytic boron conjugate additions to cyclic and acyclic unsaturated carbonyls[1]

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

PRTR

Class I Designated Chemical Substances

JAN Code

666181-250MG:4548173226293
666181-BULK:
666181-1G:4548173226286
666181-VAR:
666181-5G:4548173226309

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW4762
MKCT5307
MKCS4339
MKCQ1546
MKCL9123

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Kang-sang Lee et al.
Journal of the American Chemical Society, 131(21), 7253-7255 (2009-05-13)
Metal-free nucleophilic activation of a B-B bond has been exploited in the development of a highly efficient method for conjugate additions of commercially available bis(pinacolato)diboron to cyclic or acyclic alpha,beta-unsaturated carbonyls. The reactions are readily catalyzed by a simple N-heterocyclic

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