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Safety Information

663727

Sigma-Aldrich

2,2,2-Trichloroethoxysulfonamide

97%

Synonym(s):

2,2,2-Trichloroethyl sulfamate, Sulfamic acid, 2,2,2-trichloroethyl ester

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About This Item

Empirical Formula (Hill Notation):
C2H4Cl3NO3S
CAS Number:
69226-51-3
Molecular Weight:
228.48
MDL number:
MFCD01683146
UNSPSC Code:
12352100
PubChem Substance ID:
24884653
NACRES:
NA.22

Assay

97%

form

solid

mp

52-58 °C

SMILES string

NS(=O)(=O)OCC(Cl)(Cl)Cl

InChI

1S/C2H4Cl3NO3S/c3-2(4,5)1-9-10(6,7)8/h1H2,(H2,6,7,8)

InChI key

VOKONKGVTXWZJI-UHFFFAOYSA-N

Gene Information

human ... STS(412)

Related Categories

Application

Rh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H Amination
Nitrogen source in an intermolecular rhodium-catalyzed (662623) amination of C-H bonds.

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

>230.0 °F - closed cup

Flash Point(C)

> 110 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

663727-VAR:
663727-10G:
663727-1G:
663727-BULK:

Certificates of Analysis (COA)

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Kristin Williams Fiori et al.
Journal of the American Chemical Society, 129(3), 562-568 (2007-01-18)
Reaction methodology for intermolecular C-H amination of benzylic and 3 degrees C-H bonds is described. This process uses the starting alkane as the limiting reagent, gives optically pure tetrasubstituted amines through stereospecific insertion into enantiomeric 3 degrees centers, displays high

Articles

Rh2(esp)2 Catalyst

New! Rh2(esp)2, and exceptionally efficient and selective catalyst for C-H amination.

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