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559873

Sigma-Aldrich

Dess-Martin periodinane solution

0.3 M in methylene chloride

Synonym(s):

1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one, Dess-Martin reagent, Triacetoxyperiodinane

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About This Item

CAS Number:
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22

reaction suitability

reagent type: oxidant

concentration

0.3 M in methylene chloride

bp

40 °C

density

1.369 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC(=O)OI1(OC(C)=O)(OC(C)=O)OC(=O)c2ccccc12

InChI

1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3

InChI key

NKLCNNUWBJBICK-UHFFFAOYSA-N

Related Categories

Application

Widely used reagent for the mild oxidation of alcohols to aldehydes and ketones.

Pictograms

Health hazardExclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Central nervous system

Supplementary Hazards

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 4: Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

559873-1ML:4548173169859
559873-25ML:4548173169866
559873-VAR:
559873-5ML:4548173169873
559873-BULK:


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Dess, D. B.; Martin, J. C.
The Journal of Organic Chemistry, 48, 4155-4155 (1983)

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