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Safety Information

555134

Sigma-Aldrich

[1,1′-Bis(diphenylphosphino)ferrocene]dichlorocobalt(II)

97%

Synonym(s):

Co(dppf)Cl2, Dichloro[ferrocene-1,1′-diylbis(diphenylphosphine-P)]cobalt(II)

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About This Item

Linear Formula:
Cl2Co(P(C6H5)2C5H4)2Fe
CAS Number:
67292-36-8
Molecular Weight:
684.22
MDL number:
MFCD03427161
UNSPSC Code:
12161600
PubChem Substance ID:
24879173

Assay

97%

form

solid

reaction suitability

core: cobalt
reagent type: catalyst

mp

224 °C (dec.) (lit.)

SMILES string

[Fe].Cl[Co]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

InChI

1S/2C17H14P.2ClH.Co.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;+2;/p-2

InChI key

GODCBYSHZAJJDR-UHFFFAOYSA-L

Application

Reactant for synthesis of homoleptic complexes of cobalt(0) and nickel(0)

Catalyst for Heck-type reactions of 6-halo-1-hexene derivatives

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

555134-VAR:
555134-1G:
555134-5G:
555134-BULK:

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Certificates of Analysis (COA)

Lot/Batch Number
11929EO

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