Skip to Content
Merck
All Photos(2)

Documents

Safety Information

471569

Sigma-Aldrich

Dimethyl disulfide

≥99.0%

Synonym(s):

DMDS, Methyl disulfide

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Linear Formula:
CH3SSCH3
CAS Number:
624-92-0
Molecular Weight:
94.20
Beilstein:
1730824
EC Number:
210-871-0
MDL number:
MFCD00008561
UNSPSC Code:
12352100
PubChem Substance ID:
24870743
NACRES:
NA.22

vapor density

3.24 (vs air)

Quality Level

100

vapor pressure

22 mmHg ( 20 °C)

Assay

≥99.0%

autoignition temp.

>572 °F

expl. lim.

16 %

refractive index

n20/D 1.525 (lit.)

bp

109 °C (lit.)

mp

−85 °C (lit.)

density

1.046 g/mL at 25 °C (lit.)

SMILES string

CSSC

InChI

1S/C2H6S2/c1-3-4-2/h1-2H3

InChI key

WQOXQRCZOLPYPM-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

Dimethyl disulfide (DMDS) is an organic dialkyl disulfide. It is one of the odorous compounds found on the working face of typical municipal solid waste landfill in China. DMDS forms adducts with mono-unsaturated acetates by addition across carbon-carbon double bonds. These adducts are useful to locate the of double bonds in long-chain mono-unsaturated acetates. Adsorption of DMDS on Au(111) surface has been investigated by the density functional theory (DFT) within a generalized gradient approximation and experimental high-resolution electron energy loss spectroscopy (HREELS) techniques.

Application

Dimethyl disulfide (DMDS) may be used to derivatize alkenes for the determination of position of double bond by MS. It may also be used to determine the location of the double-bond position of monounsaturated fatty acids in Campylobacter cryaerophila by combined GC-MS analysis.

Legal Information

Product of Arkema Inc.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Sens. 1 - STOT SE 1 Inhalation - STOT SE 3

Target Organs

Central nervous system, Upper respiratory tract

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

59.0 °F - closed cup

Flash Point(C)

15 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 4: Flammable liquids
Type 1 petroleums
Hazardous rank II
Water insoluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

471569-2L:
471569-100ML:
471569-5L:
471569-25ML:4548173942124
471569-250ML:4548173942117
471569-18L:
471569-VAR:
471569-1L:4548173942100
471569-BULK:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Adsorption state of dimethyl disulfide on Au?111?: Evidence for adsorption
as thiolate at the bridge site
Hayashi T, et al.
J. Chem. Phys. , 114(17), 7615-7621 (2001)
C W Moss et al.
Journal of clinical microbiology, 27(7), 1467-1470 (1989-07-01)
Location of the double-bond position of monounsaturated fatty acids in Campylobacter cryaerophila was accomplished with combined gas chromatography-mass spectrometry analysis of dimethyl disulfide (DMDS) derivatives. The monoenoic fatty acids from whole bacterial cells were converted to methyl esters and then
Determination of double bond position in mono-unsaturated acetates by mass spectrometry of dimethyl disulfide adducts.
Buser HR, et al.
Analytical Chemistry, 55(6), 818-822 (1983)
Lu Wenjing et al.
Waste management (New York, N.Y.), 42, 74-81 (2015-05-23)
Temporal variation (seasonal and daily) of odor emission on the working face of a large sanitary landfill in China was characterized through a 2 yearlong case study. Odor pollution was most serious in spring and autumn, while lower odor concentrations
Gabrielle A Nevitt
Integrative and comparative biology, 51(5), 819-825 (2011-09-02)
Information transfer influences food-web dynamics in the marine environment, but infochemicals involved in these processes are only beginning to be understood. Dimethylsulfoniopropionate (DMSP) is produced by phytoplankton and other marine algae, and has been studied primarily in the context of
View All Related Papers

Protocols

GC Analysis of Pyrazines in Peanut Butter

Separation of various pyrazines and sulfur compounds including carbon disulfide and dimethyl disulfide.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service