Skip to Content
Merck
All Photos(1)

Documents

Safety Information

459542

Sigma-Aldrich

(R)-(−)-4-Benzyl-3-propionyl-2-oxazolidinone

99%

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C13H15NO3
CAS Number:
131685-53-5
Molecular Weight:
233.26
MDL number:
MFCD00269687
UNSPSC Code:
12352005
PubChem Substance ID:
24869569
NACRES:
NA.22

Assay

99%

form

solid

optical activity

[α]20/D −102°, c = 1 in ethanol

optical purity

ee: 99% (HPLC)

mp

44-46 °C (lit.)

SMILES string

CCC(=O)N1[C@@H](COC1=O)Cc2ccccc2

InChI

1S/C13H15NO3/c1-2-12(15)14-11(9-17-13(14)16)8-10-6-4-3-5-7-10/h3-7,11H,2,8-9H2,1H3/t11-/m1/s1

InChI key

WHOBYFHKONUTMW-LLVKDONJSA-N

General description

(R)-(−)-4-Benzyl-3-propionyl-2-oxazolidinone is used as a building block in organic synthesis for the preparation of oxazolidinone derivatives.

Application

(R)-(−)-4-Benzyl-3-propionyl-2-oxazolidinone can be used as a building block for the preparation of methyl 3-[(S)-3-((R)-4-benzyl-2-oxooxazolidin-3-yl)-2-methyl-3-oxopropyl]benzoate by treating with strong base followed by the addition of methyl 3-bromomethyl benzoate.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

459542-1G:
459542-25G:
459542-5G:
459542-BULK:
459542-VAR:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

A Synthetic Route to β-Hydroxytyrosine-Derived Tetramic Acids: Total Synthesis of the Fungal Metabolite F-14329
Bruckner, S, et al.
Chemistry?A European Journal , 23(24), 5692-5695 (2017)
Oxazolidinone cross-alkylation during Evans? asymmetric alkylation reaction
Fresno N, et al.
Tetrahedron, 67(47), 9104-9111 (2011)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service