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456411

Sigma-Aldrich

Titanium(III) chloride-aluminum chloride

TiCl3:AlCl3 3:1

Synonym(s):

Aluminum titanium chloride

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About This Item

Linear Formula:
(TiCl3)3 · AlCl3
CAS Number:
12003-13-3
Molecular Weight:
596.02
EC Number:
234-421-8
MDL number:
MFCD00083104
UNSPSC Code:
12352106
PubChem Substance ID:
24869176

form

solid

composition

TiCl3:AlCl3, 3:1

reaction suitability

reagent type: catalyst
core: titanium

SMILES string

Cl[Al](Cl)Cl.Cl[Ti](Cl)Cl.Cl[Ti](Cl)Cl.Cl[Ti](Cl)Cl

InChI

1S/Al.12ClH.3Ti/h;12*1H;;;/q+3;;;;;;;;;;;;;3*+3/p-12

InChI key

DGFMFXMKCUOBCD-UHFFFAOYSA-B

Application

Low-valent titanium is a useful reducing agent in the synthesis of imidazolines.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Pyr. Sol. 1 - Skin Corr. 1B

Supplementary Hazards

EUH014

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

456411-BULK:
456411-250G:
456411-VAR:
456411-50G:

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Certificates of Analysis (COA)

Lot/Batch Number
07421TH
11820DD
14029CO
10403HA
05517DR

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Tetrahedron Letters, 37, 4767-4767 (1996)

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