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Key Documents

Safety Information

452114

Sigma-Aldrich

Ethyl bromofluoroacetate

97%

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About This Item

Linear Formula:
BrCH(F)CO2C2H5
CAS Number:
Molecular Weight:
184.99
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

97%

refractive index

n20/D 1.424 (lit.)

bp

154 °C (lit.)

density

1.565 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CCOC(=O)C(F)Br

InChI

1S/C4H6BrFO2/c1-2-8-4(7)3(5)6/h3H,2H2,1H3

InChI key

ULNDTPIRBQGESN-UHFFFAOYSA-N

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Pictograms

Exclamation mark

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

159.8 °F - closed cup

Flash Point(C)

71 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

JAN Code

452114-BULK:
452114-1G:
452114-VAR:
452114-5G:


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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R Ocampo et al.
The Journal of organic chemistry, 67(1), 72-78 (2002-01-05)
The presence of catalytic amounts of CeCl(3) improves yields and simplifies procedure in the Reformatsky reactions of ethyl bromofluoroacetate with aldehydes and ketones to generate diastereomeric mixtures of alpha-fluoro-beta-hydroxy esters, some of which can be separated by crystallization or column
Journal of Fluorine Chemistry, 77, 45-45 (1996)
Synthesis of (E)-and (Z)-fluoro-olefin analogues of potent dipeptidyl peptidase IV inhibitors.
Van der Veken P, et al.
Tetrahedron Letters, 44(33), 6231-6234 (2003)
Thibault Ferrary et al.
Organic letters, 15(21), 5598-5601 (2013-10-22)
The synthesis of highly functionalized monofluorinated cyclopropanes based on a Michael Initiated Ring Closure (MIRC) reaction has been developed. The addition of quaternary ammonium salts derived from ethyl bromofluoroacetate on a panel of electron deficient alkenes followed by cyclization gave
Journal of the Chemical Society. Perkin Transactions 1, 49-49 (1991)

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