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437093

Sigma-Aldrich

[Bis(trimethylsilyl)acetylene](hexafluoroacetylacetonato)copper(I)

Synonym(s):

[(η2-1,2-Ethynediyl)bis[trimethylsilane]](1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-O,O′) copper

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About This Item

Linear Formula:
(CH3)3SiC≡CSi(CH3)3·[CF3COCH=C(O-)CF3]Cu
CAS Number:
Molecular Weight:
441.00
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

form

solid

reaction suitability

core: copper
reagent type: catalyst

mp

51-54 °C (lit.)

storage temp.

2-8°C

SMILES string

C[Si](C)(C)C#C[Si](C)(C)C.FC(F)(F)C(=O)\C=C(\O[Cu])C(F)(F)F

InChI

1S/C8H18Si2.C5H2F6O2.Cu/c1-9(2,3)7-8-10(4,5)6;6-4(7,8)2(12)1-3(13)5(9,10)11;/h1-6H3;1,12H;/q;;+1/p-1/b;2-1+;

InChI key

YESCMKQKTNVQCY-JITBQSAISA-M

Application

Investigations of the structure and fluorescence of copper hexafluoropentanedionate alkyne clusters

Used in chemical vapor depositing of copper
Used in chemical vapor deposition of copper.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

437093-1G:4548173940984
437093-VAR:
437093-5G:
437093-BULK:


Certificates of Analysis (COA)

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Mrs Bulletin, 19, 41-41 (1994)
Journal of the Electrochemical Society, 140, 154-154 (1993)
Materials Research Society Symposia Proceedings. Materials Research Society, 260, 629-629 (1992)

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