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436437

Sigma-Aldrich

Bis(dicyclohexylphosphino)methane

95%

Synonym(s):

Methylenebis(dicyclohexylphosphine)

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About This Item

Linear Formula:
(C6H11)2PCH2P(C6H11)2
CAS Number:
Molecular Weight:
408.58
Beilstein:
5340912
MDL number:
UNSPSC Code:
12352001
PubChem Substance ID:
NACRES:
NA.22

Assay

95%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

mp

95-102 °C (lit.)

functional group

phosphine

SMILES string

C1CCC(CC1)P(CP(C2CCCCC2)C3CCCCC3)C4CCCCC4

InChI

1S/C25H46P2/c1-5-13-22(14-6-1)26(23-15-7-2-8-16-23)21-27(24-17-9-3-10-18-24)25-19-11-4-12-20-25/h22-25H,1-21H2

InChI key

OWFLJHJHQKHZJR-UHFFFAOYSA-N

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Application

Catalyst for:
  • Ru/phosphine catalyzed anti-Markovnikov addition reactions
  • Regioselective Suzuki coupling reactions
  • Ru/phosphine catalyzed homogeneous hydrogenation reactons
  • Mediated cross-coupling reactions

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

436437-1G:
436437-BULK:
436437-VAR:
436437-5G:


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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