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429112

Sigma-Aldrich

2-Bromo-6-methylpyridine

98%

Synonym(s):

2-Bromo-6-picoline, 2-Methyl-6-bromopyridine, 6-Bromo-2-methylpyridine, 6-Bromo-2-picoline, 6-Methyl-2-bromopyridine

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About This Item

Empirical Formula (Hill Notation):
C6H6BrN
CAS Number:
5315-25-3
Molecular Weight:
172.02
EC Number:
226-173-4
MDL number:
MFCD00040743
UNSPSC Code:
12352100
PubChem Substance ID:
24866838
NACRES:
NA.22

Assay

98%

form

liquid

refractive index

n20/D 1.562 (lit.)

bp

102-103 °C/20 mmHg (lit.)

density

1.512 g/mL at 25 °C (lit.)

SMILES string

Cc1cccc(Br)n1

InChI

1S/C6H6BrN/c1-5-3-2-4-6(7)8-5/h2-4H,1H3

InChI key

SOHDPICLICFSOP-UHFFFAOYSA-N

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General description

2-Bromo-6-methylpyridine is a bromopyridine derivative. It is formed when 2-chloro-6-methylpyridine is heated with bromotrimethylsilane. Its synthesis from various methods have been reported.

Application

2-Bromo-6-methylpyridine may be used in the synthesis of the following:
  • 6,6′-dimethyl-2,2′-bipyridine
  • 6-methyl-2-pyridyl-2-pyridylmethanone
  • 2-methyl-6-(trimethylsilyl)-pyridine
  • N,N′-bis-(6-methylpyrid-2-yl)-(1R,2R)-1,2- diaminocyclohexane (cydiampy)
  • 2-methyl-6-(trimethylstannanyl)pyridine
  • 2-(6-methylpyridin-2-yl)propan-2-ol
  • bis[(2-bromo-6-methylpyridinium)hexafluorosilicate] monohydrate

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

206.6 °F - closed cup

Flash Point(C)

97 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

JAN Code

429112-10G:
429112-VAR:
429112-1G:
429112-BULK:

Certificates of Analysis (COA)

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Nickel complexes with new bidentate P,N phosphinitooxazoline and-pyridine ligands: Application for the catalytic oligomerization of ethylene.
Speiser F, et al.
Inorganic Chemistry, 43(5), 1649-1658 (2004)
3-(2-Pyridyl)-[1,2,3] triazolo [1,5-a] pyridines. An experimental and theoretical (DFT) study of the ring-chain isomerization.
Abarca B, et al.
Organic & Biomolecular Chemistry, 3(21), 3905-3910 (2005)
Preparation, structure and properties of pyridinium/bipyridinium hexafluorosilicates.
Gelmboldt VO, et al.
Journal of Fluorine Chemistry, 160, 57-63 (2014)
Synthesis of Dimethylbipyridines by the Reductive Coupling of 2-Halomethylpyridines with Nickel Catalyst.
Rajalakshmanan E and Alexander V.
Synthetic Communications, 35(6), 891-895 (2005)
Crystallographic report:[N,N'-Bis-(6-methylpyrid-2-ylium)-(1R, 2R)-1,2-diaminocyclohexane] bis-[(p-cymene)-trichlororuthenate(II)].
Cabeza JA, et al.
Applied Organometallic Chemistry, 19(1), 209-210 (2005)
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