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422843

Sigma-Aldrich

Potassium trifluoromethanesulfonate

98%

Synonym(s):

Potassium triflate, Trifluoromethanesulfonic acid potassium salt

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About This Item

Linear Formula:
CF3SO3K
CAS Number:
2926-27-4
Molecular Weight:
188.17
Beilstein:
3727495
MDL number:
MFCD00042370
UNSPSC Code:
12352100
PubChem Substance ID:
24866458
NACRES:
NA.22

Assay

98%

form

powder

SMILES string

[K+].[O-]S(=O)(=O)C(F)(F)F

InChI

1S/CHF3O3S.K/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1

InChI key

GLGXXYFYZWQGEL-UHFFFAOYSA-M

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General description

Potassium trifluoromethanesulfonate (KOTf, potassium triflate) is the potassium salt of trifluoromethanesulphonic acid. It has been prepared by neutralizing a warm aqueous solution of trifluoromethanesulphonic acid with potassium carbonate. The structure of siloxane–poly(oxyethylene) hybrids doped with potassium triflate has been investigated.

Application

Potassium trifluoromethanesulfonate (potassium triflate) is suitable as a reagent in the synthesis of guanine-quadruplex hybrid materials by the self-assembly of a guanine-siloxane monomer.
It may be used in the following studies:
  • As a template source for constructing the heterotopic isothiosemicarbazide-based macrocyclic ligand.
  • As a supporting electrolyte in the electrochemical study of evidence for gold anion in ethylenediamine.
  • As a reagent in the synthesis of imidazolium salt, 3-methyl-1-(3R,3aR,6S,6aR)-[6-(benzyloxy)-hexahydrofuro[3,2-b]furan-3-yl]imidazolium trifluoromethanesulfonate.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

422843-BULK:
422843-5G:
422843-VAR:
422843-25G:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Gregory D Bowden et al.
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Recent advancements in 18F radiochemistry, such as the advent of copper-mediated radiofluorination (CMRF) chemistry, have provided unprecedented access to novel chemically diverse PET probes; however, these multicomponent reactions have come with a new set of complex optimization problems. Design of
Evidence for the gold anion in ethylenediamine.
Jagannathan R, et al.
Inorganic Chemistry, 24(1), 113-114 (1985)
Local and nanoscopic structure of potassium triflate-doped siloxane-polyoxyethylene ormolytes.
Chaker JA, et al.
Journal of Non-Crystalline Solids, 352(32), 3457-3462 (2006)
Sol-gel selection of hybrid G-quadruplex architectures from dynamic supramolecular guanosine libraries.
Mihai S, et al.
Journal of Materials Chemistry, 20(42), 9443-9448 (2010)
Potassium-controlled synthesis of heterotopic macrocycles based on isothiosemicarbazide.
Arion VB, et al.
Inorgorganica Chimica Acta, 328(1), 123-133 (2002)
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