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412791

Sigma-Aldrich

N,O-Di-Boc-hydroxylamine

97%

Synonym(s):

N,O-Bis(tert-butoxycarbonyl)hydroxylamine, tert-Butyl N-(tert-butoxycarbonyloxy)carbamate

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5 G
¥13,300

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5 G
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About This Item

Linear Formula:
(CH3)3COCONHOCOOC(CH3)3
CAS Number:
85006-25-3
Molecular Weight:
233.26
Beilstein:
1794022
EC Number:
285-055-0
MDL number:
MFCD00034797
UNSPSC Code:
12352100
PubChem Substance ID:
24865823
NACRES:
NA.22

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Assay

97%

mp

67-70 °C (lit.)

functional group

amine

storage temp.

−20°C

SMILES string

CC(C)(C)OC(=O)NOC(=O)OC(C)(C)C

InChI

1S/C10H19NO5/c1-9(2,3)14-7(12)11-16-8(13)15-10(4,5)6/h1-6H3,(H,11,12)

InChI key

AGOSGCWATIJZHQ-UHFFFAOYSA-N

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Application

N,O-Di-Boc-hydroxylamine (N,O-Bis(tert-butoxycarbonyl)hydroxylamine) may be used for the synthesis of the following:
  • 5-lipoxygenase inhibitor LY280810[1]
  • hydroxylamines[1]
  • hydroxamic acids[1],[2]

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

412791-BULK:
412791-VAR:
412791-5G:
412791-1G:

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Certificates of Analysis (COA)

Lot/Batch Number
0001451885
1451885V
1451885
044630/1
08928PN

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The use of N, O-bis (tert-butoxycarbonyl)-hydroxylamine in the synthesis of N-hydroxylamines and hydroxamic acids.
Staszak MA and Doecke CW.
Tetrahedron Letters, 35(23), 6021-6024 (1994)
A facile synthesis of N, O-bis (tert-butoxycarbonyl)-hydroxylamine.
Staszak MA and Doecke CW.
Tetrahedron Letters, 34(44), 7043-7044 (1993)
A convenient method for the preparation of hydroxamic acids.
Reddy AS, et al.
Tetrahedron Letters, 41(33), 6285-6288 (2000)

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