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412643

Sigma-Aldrich

Geranylamine

90%

Synonym(s):

trans-3,7-Dimethyl-2,6-octadien-1-ylamine, trans-3,7-Dimethyl-2,6-octadienyl amine

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About This Item

Linear Formula:
(CH3)2C=CHCH2CH2C(CH3)=CHCH2NH2
CAS Number:
Molecular Weight:
153.26
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

90%

form

liquid

refractive index

n20/D 1.476 (lit.)

bp

105 °C/19 mmHg (lit.)

density

0.829 g/mL at 25 °C (lit.)

SMILES string

[H]\C(CN)=C(\C)CC\C=C(\C)C

InChI

1S/C10H19N/c1-9(2)5-4-6-10(3)7-8-11/h5,7H,4,6,8,11H2,1-3H3/b10-7+

InChI key

AFMZGMJNKXOLEM-JXMROGBWSA-N

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General description

Geranylamine is an di-isoprene derivative.

Application

Geranylamine may be employed as starting reagent for the total synthesis of a naturally occurring guanidine alkaloid, Nitensidine D. It may be used for the synthesis of 5-alkylamino- and 2,5-bis(alkylamino)-[1,4]-benzoquinone.

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

190.4 °F - closed cup

Flash Point(C)

88 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

JAN Code

412643-BULK:
412643-5G:
412643-VAR:
412643-1G:


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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First total synthesis of a guanidine alkaloid Nitensidine D using immobilized ionic liquid, microwaves and formamidinesulfinic acid.
SHARMA ML and SINGH J.
Journal of Chemical Sciences (Bangalore), 126(6), 1869-1874 (2014)
Laccase-mediated synthesis of 2-methoxy-3-methyl-5-(alkylamino)-and 3-methyl-2, 5-bis (alkylamino)-[1, 4]-benzoquinones.
Herter S, et al.
Journal of Molecular Catalysis. B, Enzymatic, 90, 91-97 (2013)

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