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Safety Information

399949

Sigma-Aldrich

Vanadium(V) oxyfluoride

99%

Synonym(s):

Vanadium(V) oxytrifluoride, Vanadyl trifluoride

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About This Item

Linear Formula:
VOF3
CAS Number:
13709-31-4
Molecular Weight:
123.94
EC Number:
237-250-7
MDL number:
MFCD00042555
UNSPSC Code:
12352302
PubChem Substance ID:
24864853
NACRES:
NA.23

Quality Level

100

Assay

99%

form

powder

reaction suitability

reagent type: catalyst
core: vanadium

solubility

H2O: insoluble(lit.)

application(s)

battery manufacturing

SMILES string

F[V](F)(F)=O

InChI

1S/3FH.O.V/h3*1H;;/q;;;;+3/p-3

InChI key

FXGIDXZUDLFPLD-UHFFFAOYSA-K

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Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302 + H312 + H332,H314

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Supplementary Hazards

EUH032

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

JAN Code

399949-VAR:
399949-25G:
399949-BULK:
399949-5G:

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Certificates of Analysis (COA)

Lot/Batch Number
MKBR0897V
MKBP1305V
MKBG7657V
MKBB9347
06607HH

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Micah J Niphakis et al.
Organic letters, 13(2), 196-199 (2010-12-15)
A highly convergent strategy to prepare phenanthroindolizidines is reported involving three consecutive C-C coupling reactions. This sequence features a novel VOF(3)-mediated aryl-alkene coupling in the final step, which enables regioselective preparation of C5-substituted phenanthroindolizidines for the first time. This strategy
M D Zidan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 56(14), 2693-2698 (2001-01-06)
A new route has been devised, leading to the production of VOX3 molecules where X=F, Br and I by an on-line process using vanadium oxytrichloride, VOCl3 as a starting compound passed over the following heated salts NaF, KBr and KI

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