Skip to Content
Merck
All Photos(1)

Documents

Safety Information

398306

Sigma-Aldrich

Palladium(II) sulfide

99.9% trace metals basis

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
PdS
CAS Number:
12125-22-3
Molecular Weight:
138.49
EC Number:
235-190-6
MDL number:
MFCD00016285
UNSPSC Code:
12352300
PubChem Substance ID:
24864736

Assay

99.9% trace metals basis

form

solid

reaction suitability

reagent type: catalyst
core: palladium

density

6.6 g/mL at 25 °C (lit.)

SMILES string

S=[Pd]

InChI

1S/Pd.S

InChI key

NRUVOKMCGYWODZ-UHFFFAOYSA-N

General description

Palladium sulfide can be formed from allyl palladium dithiocarbamates and dithiolate complexes by metal organic chemical vapor deposition (MOCVD). Enthalpy of formation of the Pd-S system has been investigated by mixing calorimetry method.

Application

PdS organosol can be prepared by reacting the metal acetate with hydrogen sulfide. These organo sols may be further utilized to form polymer metal sulfide composites. Palladium sulfide may be used to catalyze the hydrogenation of thiopene.

Packaging

Packaged in glass bottles

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

398306-BULK:
398306-1G:
398306-VAR:
398306-5G:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

New organosols of nickel sulfides, palladium sulfides, manganese sulfide, and mixed metal sulfides and their use in preparation of semiconducting polymer-metal sulfide composites.
Yamamoto T, et al.
Colloid and Polymer Science, 269(10), 969-971 (1991)
Enthalpies of formation of the palladium sulphides
Zubkov A, et al.
The Journal of Chemical Thermodynamics, 30(5), 571-581 (1998)
Kinetic study of catalytic hydrogenation of thiophene on a palladium sulfide catalyst.
Ermakova A, et al.
Kinetics and Catalysis, 43(4), 528-536 (2002)
Allyl palladium dithiocarbamates and related dithiolate complexes as precursors to palladium sulfides
Birri A, et al.
Journal of Organometallic Chemistry, 692(12), 2448- 2455 (2007)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service