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393258

Sigma-Aldrich

Bis(2-carbopentyloxy-3,5,6-trichlorophenyl) oxalate

technical grade

Synonym(s):

CPPO

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About This Item

Linear Formula:
[CO2C6H(Cl)3CO2(CH2)4CH3]2
CAS Number:
75203-51-9
Molecular Weight:
677.18
EC Number:
278-124-1
MDL number:
MFCD00012038
UNSPSC Code:
12352103
PubChem Substance ID:
57649894
NACRES:
NA.23

grade

technical grade

Assay

≥96.5% (by AgNO3, titration)

form

solid

mp

76-80 °C (lit.)

SMILES string

CCCCCOC(=O)c1c(Cl)cc(Cl)c(Cl)c1OC(=O)C(=O)Oc2c(Cl)c(Cl)cc(Cl)c2C(=O)OCCCCC

InChI

1S/C26H24Cl6O8/c1-3-5-7-9-37-23(33)17-13(27)11-15(29)19(31)21(17)39-25(35)26(36)40-22-18(14(28)12-16(30)20(22)32)24(34)38-10-8-6-4-2/h11-12H,3-10H2,1-2H3

InChI key

PURKHUDOTFUVNG-UHFFFAOYSA-N

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General description

Bis(2-carbopentyloxy-3,5,6-trichlorophenyl) oxalate is a peroxyoxalate based material that is used as in chemiluminescent dye which can further be utilized as a detection method for liquid phase analysis. It can be solubilized in organic solvents to achieve high quantum efficiencies and produce a strong chemiluminescent blue light.[1][2][3][4]

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

393258-BULK:
393258-1G:
393258-5G:
393258-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCG3840
MKBM8409V
12001HO
08617AG
04013LF

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Chemiluminescent properties of copolyesters containing red and blue chromophores.
Lee CW, et al.
Synthetic Metals, 126(1), 97-104 (2002)
Chemiluminescent properties of blue fluorophores containing naphthalene unit.
Cheon JW, et al.
Dyes and Pigments, 61(1), 23-30 (2004)
Thin-film organic photodiodes as integrated detectors for microscale chemiluminescence assays.
Hofmann O, et al.
Sensors and Actuators B, Chemical, 106(2), 878-884 (2005)
Improved microfluidic chip-based sequential-injection trapped-droplet array liquid-liquid extraction system for determination of aluminium.
Shen H and Fang Q
Talanta, 77(1), 269-272 (2008)

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