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365386

Sigma-Aldrich

N,N-Diisopropylcarbamoyl chloride

98%

Synonym(s):

Diisopropylcarbamic chloride, Diisopropylcarbamyl chloride, N,N-Bis(1-methylethyl)carbamic chloride

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5 G
¥10,900
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¥27,300

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5 G
¥10,900
25 G
¥27,300

About This Item

Linear Formula:
[(CH3)2CH]2NCOCl
CAS Number:
19009-39-3
Molecular Weight:
163.65
Beilstein:
1754834
EC Number:
242-743-5
MDL number:
MFCD00015013
UNSPSC Code:
12352100
PubChem Substance ID:
24862514
NACRES:
NA.22

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Assay

98%

form

solid

bp

90-93 °C/15 mmHg (lit.)

mp

57-59 °C (lit.)

functional group

amine
chloro

SMILES string

CC(C)N(C(C)C)C(Cl)=O

InChI

1S/C7H14ClNO/c1-5(2)9(6(3)4)7(8)10/h5-6H,1-4H3

InChI key

RSAFAYLZKCYUQW-UHFFFAOYSA-N

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Application

N,N-Diisopropylcarbamoyl chloride may be used in the preparation of:
  • 1-aryl-1-alkenyl N,N-diisopropylcarbamates[1]
  • 1,3-diphenylallyl carbamate[2]
  • (Z)-1,3-diphenyl-1-propenyl N,N-diisopropylcarbamate[2]
  • (R)-1-(2-methoxy-4-methylphenyl)ethyl diisopropyl-carbamate[3]

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

365386-25G:
365386-VAR:
365386-BULK:
365386-5G:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCR7409
MKCL3207
MKBZ0029V
MKBR1075V
SHBB3055V

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The total synthesis of (-)-aplysin via a lithiation-borylation-propenylation sequence.
Fletcher CJ, et al.
Tetrahedron, 68(23), 7598-7604 (2012)
Stereoselective Intermolecular Carbolithiation of Open-Chain and Cyclic 1-Aryl-1-alkenyl N,N-Diisopropylcarbamates Coupled with Electrophilic Substitution. Observation of p-Carboxylation in a Benzyllithium Derivative.
Peters JG, et al.
Synthesis, 03, 0381-0292 (2002)
Asymmetric ?-Deprotonation and Substitution Reactions of (Z)-1, 3-Diphenyl-1-propenyl N, N-Diisopropylcarbamate.
Reuber J, et al.
European Journal of Organic Chemistry, 14, 3017-3025 (2005)

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