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339725

Sigma-Aldrich

Chloromethane solution

1.0 M in tert-butyl methyl ether, anhydrous

Synonym(s):

Methyl chloride

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¥39,700

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About This Item

Empirical Formula (Hill Notation):
CH3Cl
CAS Number:
74-87-3
Molecular Weight:
50.49
MDL number:
MFCD00000872
UNSPSC Code:
12352100
PubChem Substance ID:
24860670
NACRES:
NA.22

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grade

anhydrous

form

liquid

concentration

1.0 M in tert-butyl methyl ether

impurities

<0.005% water

density

0.765 g/mL at 25 °C

functional group

alkyl halide
chloro

storage temp.

2-8°C

SMILES string

CCl

InChI

1S/CH3Cl/c1-2/h1H3

InChI key

NEHMKBQYUWJMIP-UHFFFAOYSA-N

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General description

Radiolysis of aqueous solutions of chloromethanes was performed with γ-rays.[1] Dechlorination of chloromethane on iron and palladium-iron bimetallic surface in aqueous systems has been reported.[2]

Packaging

Supplied in a Sure/Pac™ cylinder and has a 1/4-turn bronze ball valve with a female 1/4" NPT outlet thread (Z122661) installed. Before using the cylinder, ensure that the valve is closed, then remove carbon steel plug that seals the outlet valve.

Compatible with the following:For instructions please refer to technical bulletin AL-136: The Aldrich Sure/Pac™ Cylinder System

Legal Information

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

also commonly purchased with this product

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recommended

Product No.
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septum inlet adapter

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Signal Word

Danger

Hazard Classifications

Carc. 2 - Flam. Liq. 2 - Ozone 1 - Repr. 2 - Skin Irrit. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

-29.2 °F - closed cup

Flash Point(C)

-34 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

PRTR

Class I Designated Chemical Substances

FSL

Group 4: Flammable liquids
Special flammables
Hazardous rank I

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

339725-VAR:
339725-BULK:
339725-200ML:4548173137476

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Certificates of Analysis (COA)

Lot/Batch Number
SHBR5461
SHBR0428
SHBM9236
SHBJ8942
SHBH7764

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Dechlorination of chloromethanes on iron and palladium-iron bimetallic surface in aqueous systems.
Wan C, et al
Environmental Toxicology and Chemistry / Setac, 18(6), 1091-1096 (1999)
Xiaofeng Tang et al.
The Journal of chemical physics, 136(3), 034304-034304 (2012-01-28)
Utilizing threshold photoelectron-photoion coincidence (TPEPICO) velocity imaging, dissociation of state-selected CH(3)Cl(+) ions was investigated in the excitation energy range of 11.0-18.5 eV. TPEPICO time-of-flight mass spectra and three-dimensional time-sliced velocity images of CH(3)(+) dissociated from CH(3)Cl(+)(A(2)A(1) and B(2)E) ions were
High dose radiolysis of aqueous solutions of chloromethanes: Importance in the storage of radioactive organic wastes.
Rajesh P, et al.
Journal of Nuclear Materials, 361(1), 10-17 (2007)
L El Khoury et al.
The Journal of chemical physics, 136(2), 024319-024319 (2012-01-21)
We present a combined experimental and theoretical study of isolated CH(3)Cl molecules using resonant inelastic x-ray scattering (RIXS). The high-resolution spectra allow extraction of information about nuclear dynamics in the core-excited molecule. Polarization-resolved RIXS spectra exhibit linear dichroism in the
Francesca Bleken et al.
The journal of physical chemistry. A, 114(27), 7391-7397 (2010-06-19)
The methylation of ethene by methyl chloride and methanol in the microporous materials SAPO-34 and SSZ-13 has been studied using different periodic atomistic modeling approaches based on density functional theory. The RPBE functional, which earlier has been used successfully in
View All Related Papers

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